Hexa­kis­(dimethyl sulfoxide-κO)thallium(III) trinitrate

The title compound, [Tl(C(2)H(6)OS)(6)](NO(3))(3), consists of six dimethyl sulfoxide (DMSO) mol­ecules coordinated to a Tl(III) atom, which lies on a [Image: see text] axis, and three nitrate anions (3. symmetry) to neutralize the charge. The coordination polyhedron around the Tl(III) atom is octa­...

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Detalles Bibliográficos
Autores principales: Ghadermazi, Mohammad, Manteghi, Faranak
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006801/
https://www.ncbi.nlm.nih.gov/pubmed/21587730
http://dx.doi.org/10.1107/S1600536810022646
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author Ghadermazi, Mohammad
Manteghi, Faranak
author_facet Ghadermazi, Mohammad
Manteghi, Faranak
author_sort Ghadermazi, Mohammad
collection PubMed
description The title compound, [Tl(C(2)H(6)OS)(6)](NO(3))(3), consists of six dimethyl sulfoxide (DMSO) mol­ecules coordinated to a Tl(III) atom, which lies on a [Image: see text] axis, and three nitrate anions (3. symmetry) to neutralize the charge. The coordination polyhedron around the Tl(III) atom is octa­hedral, defined by six O atoms of the DMSO mol­ecules. In the crystal structure, C—H⋯O hydrogen bonds are observed. One of the nitrate groups exhibits half-occupation.
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spelling pubmed-30068012010-12-30 Hexa­kis­(dimethyl sulfoxide-κO)thallium(III) trinitrate Ghadermazi, Mohammad Manteghi, Faranak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Tl(C(2)H(6)OS)(6)](NO(3))(3), consists of six dimethyl sulfoxide (DMSO) mol­ecules coordinated to a Tl(III) atom, which lies on a [Image: see text] axis, and three nitrate anions (3. symmetry) to neutralize the charge. The coordination polyhedron around the Tl(III) atom is octa­hedral, defined by six O atoms of the DMSO mol­ecules. In the crystal structure, C—H⋯O hydrogen bonds are observed. One of the nitrate groups exhibits half-occupation. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3006801/ /pubmed/21587730 http://dx.doi.org/10.1107/S1600536810022646 Text en © Ghadermazi and Manteghi 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ghadermazi, Mohammad
Manteghi, Faranak
Hexa­kis­(dimethyl sulfoxide-κO)thallium(III) trinitrate
title Hexa­kis­(dimethyl sulfoxide-κO)thallium(III) trinitrate
title_full Hexa­kis­(dimethyl sulfoxide-κO)thallium(III) trinitrate
title_fullStr Hexa­kis­(dimethyl sulfoxide-κO)thallium(III) trinitrate
title_full_unstemmed Hexa­kis­(dimethyl sulfoxide-κO)thallium(III) trinitrate
title_short Hexa­kis­(dimethyl sulfoxide-κO)thallium(III) trinitrate
title_sort hexa­kis­(dimethyl sulfoxide-κo)thallium(iii) trinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006801/
https://www.ncbi.nlm.nih.gov/pubmed/21587730
http://dx.doi.org/10.1107/S1600536810022646
work_keys_str_mv AT ghadermazimohammad hexakisdimethylsulfoxidekothalliumiiitrinitrate
AT manteghifaranak hexakisdimethylsulfoxidekothalliumiiitrinitrate

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