{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(thio­cyanato-κN)manganese(II)

The mol­ecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thio­cyanate ligands, forming a d...

Descripción completa

Detalles Bibliográficos
Autor principal: Wang, Fu-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006804/
https://www.ncbi.nlm.nih.gov/pubmed/21587704
http://dx.doi.org/10.1107/S1600536810021550
Descripción
Sumario:The mol­ecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thio­cyanate ligands, forming a distorted octa­hedral geometry.

Ejemplares similares