Cargando…
{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
The molecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thiocyanate ligands, forming a d...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006804/ https://www.ncbi.nlm.nih.gov/pubmed/21587704 http://dx.doi.org/10.1107/S1600536810021550 |
_version_ | 1782194226154438656 |
---|---|
author | Wang, Fu-Ming |
author_facet | Wang, Fu-Ming |
author_sort | Wang, Fu-Ming |
collection | PubMed |
description | The molecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thiocyanate ligands, forming a distorted octahedral geometry. |
format | Text |
id | pubmed-3006804 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30068042010-12-30 {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) Wang, Fu-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thiocyanate ligands, forming a distorted octahedral geometry. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006804/ /pubmed/21587704 http://dx.doi.org/10.1107/S1600536810021550 Text en © Fu-Ming Wang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Fu-Ming {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(4)
N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title_full | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(4)
N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title_fullStr | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(4)
N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title_full_unstemmed | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(4)
N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title_short | {N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(4)
N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
title_sort | {n,n′-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(4)
n,n′,n′′,n′′′}bis(thiocyanato-κn)manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006804/ https://www.ncbi.nlm.nih.gov/pubmed/21587704 http://dx.doi.org/10.1107/S1600536810021550 |
work_keys_str_mv | AT wangfuming nnbis12pyridylethylideneethane12diaminek4nnnnbisthiocyanatoknmanganeseii |