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{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(thio­cyanato-κN)manganese(II)

The mol­ecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thio­cyanate ligands, forming a d...

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Detalles Bibliográficos
Autor principal: Wang, Fu-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006804/
https://www.ncbi.nlm.nih.gov/pubmed/21587704
http://dx.doi.org/10.1107/S1600536810021550
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author Wang, Fu-Ming
author_facet Wang, Fu-Ming
author_sort Wang, Fu-Ming
collection PubMed
description The mol­ecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thio­cyanate ligands, forming a distorted octa­hedral geometry.
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spelling pubmed-30068042010-12-30 {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(thio­cyanato-κN)manganese(II) Wang, Fu-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thio­cyanate ligands, forming a distorted octa­hedral geometry. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006804/ /pubmed/21587704 http://dx.doi.org/10.1107/S1600536810021550 Text en © Fu-Ming Wang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Fu-Ming
{N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(thio­cyanato-κN)manganese(II)
title {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(thio­cyanato-κN)manganese(II)
title_full {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(thio­cyanato-κN)manganese(II)
title_fullStr {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(thio­cyanato-κN)manganese(II)
title_full_unstemmed {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(thio­cyanato-κN)manganese(II)
title_short {N,N′-Bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis­(thio­cyanato-κN)manganese(II)
title_sort {n,n′-bis[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(4) n,n′,n′′,n′′′}bis­(thio­cyanato-κn)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006804/
https://www.ncbi.nlm.nih.gov/pubmed/21587704
http://dx.doi.org/10.1107/S1600536810021550
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