Penta­kis(ethyl­enediammonium) tri-μ-sulfato-bis­[tris­ulfatocerate(IV)] trihydrate

In the cerate(IV) anion of the title salt, (C(2)H(10)N(2))(5)[Ce(2)(SO(4))(9)]·3H(2)O, the two metal atoms are bridged by three sulfate units; each metal atom is itself chelated by other three sulfate units so that the metal atoms exist in nine-coordinate tricapped trigonal-prismatic geometries. The...

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Autores principales: Jabeen, Nadia, Ahmad, Saeed, Meer, Ali Farooq, Khan, Islam Ullah, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006805/
https://www.ncbi.nlm.nih.gov/pubmed/21587720
http://dx.doi.org/10.1107/S1600536810021811
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author Jabeen, Nadia
Ahmad, Saeed
Meer, Ali Farooq
Khan, Islam Ullah
Ng, Seik Weng
author_facet Jabeen, Nadia
Ahmad, Saeed
Meer, Ali Farooq
Khan, Islam Ullah
Ng, Seik Weng
author_sort Jabeen, Nadia
collection PubMed
description In the cerate(IV) anion of the title salt, (C(2)H(10)N(2))(5)[Ce(2)(SO(4))(9)]·3H(2)O, the two metal atoms are bridged by three sulfate units; each metal atom is itself chelated by other three sulfate units so that the metal atoms exist in nine-coordinate tricapped trigonal-prismatic geometries. The anions, cations and uncoordinated water mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional network. One of the five cations is disordered with respect to the ethyl­ene portion in a 1:1 ratio.
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spelling pubmed-30068052010-12-30 Penta­kis(ethyl­enediammonium) tri-μ-sulfato-bis­[tris­ulfatocerate(IV)] trihydrate Jabeen, Nadia Ahmad, Saeed Meer, Ali Farooq Khan, Islam Ullah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cerate(IV) anion of the title salt, (C(2)H(10)N(2))(5)[Ce(2)(SO(4))(9)]·3H(2)O, the two metal atoms are bridged by three sulfate units; each metal atom is itself chelated by other three sulfate units so that the metal atoms exist in nine-coordinate tricapped trigonal-prismatic geometries. The anions, cations and uncoordinated water mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional network. One of the five cations is disordered with respect to the ethyl­ene portion in a 1:1 ratio. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006805/ /pubmed/21587720 http://dx.doi.org/10.1107/S1600536810021811 Text en © Jabeen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jabeen, Nadia
Ahmad, Saeed
Meer, Ali Farooq
Khan, Islam Ullah
Ng, Seik Weng
Penta­kis(ethyl­enediammonium) tri-μ-sulfato-bis­[tris­ulfatocerate(IV)] trihydrate
title Penta­kis(ethyl­enediammonium) tri-μ-sulfato-bis­[tris­ulfatocerate(IV)] trihydrate
title_full Penta­kis(ethyl­enediammonium) tri-μ-sulfato-bis­[tris­ulfatocerate(IV)] trihydrate
title_fullStr Penta­kis(ethyl­enediammonium) tri-μ-sulfato-bis­[tris­ulfatocerate(IV)] trihydrate
title_full_unstemmed Penta­kis(ethyl­enediammonium) tri-μ-sulfato-bis­[tris­ulfatocerate(IV)] trihydrate
title_short Penta­kis(ethyl­enediammonium) tri-μ-sulfato-bis­[tris­ulfatocerate(IV)] trihydrate
title_sort penta­kis(ethyl­enediammonium) tri-μ-sulfato-bis­[tris­ulfatocerate(iv)] trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006805/
https://www.ncbi.nlm.nih.gov/pubmed/21587720
http://dx.doi.org/10.1107/S1600536810021811
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