tert-Butyl 2-[4-(2-{4-[(tert-butoxycar­bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate

In the mol­ecule of the title compound, C(29)H(40)O(6), the carbon atom belonging to the propyl chain is connected to two aromatic rings that open up the C(ar­yl)—C—C(ar­yl) angle to 111.5 (1)°. The four-atom –O–CH(2)–C(=O)–O– linkage between the aromatic ring and the tert-butyl group assumes a (−)a...

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Detalles Bibliográficos
Autores principales: Ali, Qamar, Yousuf, Sammer, Raza Shah, Muhammad, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006808/
https://www.ncbi.nlm.nih.gov/pubmed/21587966
http://dx.doi.org/10.1107/S1600536810023433
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author Ali, Qamar
Yousuf, Sammer
Raza Shah, Muhammad
Ng, Seik Weng
author_facet Ali, Qamar
Yousuf, Sammer
Raza Shah, Muhammad
Ng, Seik Weng
author_sort Ali, Qamar
collection PubMed
description In the mol­ecule of the title compound, C(29)H(40)O(6), the carbon atom belonging to the propyl chain is connected to two aromatic rings that open up the C(ar­yl)—C—C(ar­yl) angle to 111.5 (1)°. The four-atom –O–CH(2)–C(=O)–O– linkage between the aromatic ring and the tert-butyl group assumes a (−)anti-periplanar conformation for one substituent and a (−)syn-periplanar conformation for the other substituent; the O–C–C–O torsion angles are −173.7 (2) and −10.2 (3)°.
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spelling pubmed-30068082010-12-30 tert-Butyl 2-[4-(2-{4-[(tert-butoxycar­bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate Ali, Qamar Yousuf, Sammer Raza Shah, Muhammad Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(29)H(40)O(6), the carbon atom belonging to the propyl chain is connected to two aromatic rings that open up the C(ar­yl)—C—C(ar­yl) angle to 111.5 (1)°. The four-atom –O–CH(2)–C(=O)–O– linkage between the aromatic ring and the tert-butyl group assumes a (−)anti-periplanar conformation for one substituent and a (−)syn-periplanar conformation for the other substituent; the O–C–C–O torsion angles are −173.7 (2) and −10.2 (3)°. International Union of Crystallography 2010-06-23 /pmc/articles/PMC3006808/ /pubmed/21587966 http://dx.doi.org/10.1107/S1600536810023433 Text en © Ali et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ali, Qamar
Yousuf, Sammer
Raza Shah, Muhammad
Ng, Seik Weng
tert-Butyl 2-[4-(2-{4-[(tert-butoxycar­bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate
title tert-Butyl 2-[4-(2-{4-[(tert-butoxycar­bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate
title_full tert-Butyl 2-[4-(2-{4-[(tert-butoxycar­bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate
title_fullStr tert-Butyl 2-[4-(2-{4-[(tert-butoxycar­bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate
title_full_unstemmed tert-Butyl 2-[4-(2-{4-[(tert-butoxycar­bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate
title_short tert-Butyl 2-[4-(2-{4-[(tert-butoxycar­bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate
title_sort tert-butyl 2-[4-(2-{4-[(tert-butoxycar­bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006808/
https://www.ncbi.nlm.nih.gov/pubmed/21587966
http://dx.doi.org/10.1107/S1600536810023433
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AT yousufsammer tertbutyl2424tertbutoxycarbonylmethoxy3methylphenyl2propyl2methylphenoxyacetate
AT razashahmuhammad tertbutyl2424tertbutoxycarbonylmethoxy3methylphenyl2propyl2methylphenoxyacetate
AT ngseikweng tertbutyl2424tertbutoxycarbonylmethoxy3methylphenyl2propyl2methylphenoxyacetate

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