Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,3-diol solvate

In the structure of the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Ni(II) ion (site symmetry 2) is six-coordinated in a distorted octa­hedral manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and two O atoms from a bidentate sulfate ligand (2 symmetry)...

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Detalles Bibliográficos
Autores principales: Ni, Chao, Zhong, Kai-Long, Cui, Jiang-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006809/
https://www.ncbi.nlm.nih.gov/pubmed/21587684
http://dx.doi.org/10.1107/S1600536810020210
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author Ni, Chao
Zhong, Kai-Long
Cui, Jiang-Dong
author_facet Ni, Chao
Zhong, Kai-Long
Cui, Jiang-Dong
author_sort Ni, Chao
collection PubMed
description In the structure of the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Ni(II) ion (site symmetry 2) is six-coordinated in a distorted octa­hedral manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and two O atoms from a bidentate sulfate ligand (2 symmetry). The dihedral angle between the two chelating NCCN groups is 80.9 (1)°. The central C atom of the propane-1,3-diol solvent mol­ecule is likewise located on a twofold rotation axis. In the crystal structure, the [Ni(SO(4))(C(12)H(8)N(2))(2)] and C(3)H(8)O(2) entities are connected through inter­molecular O—H⋯O hydrogen bonding.
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spelling pubmed-30068092010-12-30 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,3-diol solvate Ni, Chao Zhong, Kai-Long Cui, Jiang-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Ni(II) ion (site symmetry 2) is six-coordinated in a distorted octa­hedral manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and two O atoms from a bidentate sulfate ligand (2 symmetry). The dihedral angle between the two chelating NCCN groups is 80.9 (1)°. The central C atom of the propane-1,3-diol solvent mol­ecule is likewise located on a twofold rotation axis. In the crystal structure, the [Ni(SO(4))(C(12)H(8)N(2))(2)] and C(3)H(8)O(2) entities are connected through inter­molecular O—H⋯O hydrogen bonding. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006809/ /pubmed/21587684 http://dx.doi.org/10.1107/S1600536810020210 Text en © Ni et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ni, Chao
Zhong, Kai-Long
Cui, Jiang-Dong
Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,3-diol solvate
title Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,3-diol solvate
title_full Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,3-diol solvate
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,3-diol solvate
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,3-diol solvate
title_short Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)nickel(II) propane-1,3-diol solvate
title_sort bis(1,10-phenanthroline-κ(2) n,n′)(sulfato-κ(2) o,o′)nickel(ii) propane-1,3-diol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006809/
https://www.ncbi.nlm.nih.gov/pubmed/21587684
http://dx.doi.org/10.1107/S1600536810020210
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AT zhongkailong bis110phenanthrolinek2nnsulfatok2oonickeliipropane13diolsolvate
AT cuijiangdong bis110phenanthrolinek2nnsulfatok2oonickeliipropane13diolsolvate

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