9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca­borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9))

The asymmetric unit of the title compound, C(6)H(16)B(10), contains one mol­ecule that is close to possessing a non-crystallographic plane of mirror symmetry in the space group Pna2(1). The orientation of the mol­ecules in the ortho­rhom­bic cell shows that the structure can not be described in the...

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Detalles Bibliográficos
Autores principales: Finze, Maik, Reiss, Guido J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006814/
https://www.ncbi.nlm.nih.gov/pubmed/21587928
http://dx.doi.org/10.1107/S1600536810022440
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author Finze, Maik
Reiss, Guido J.
author_facet Finze, Maik
Reiss, Guido J.
author_sort Finze, Maik
collection PubMed
description The asymmetric unit of the title compound, C(6)H(16)B(10), contains one mol­ecule that is close to possessing a non-crystallographic plane of mirror symmetry in the space group Pna2(1). The orientation of the mol­ecules in the ortho­rhom­bic cell shows that the structure can not be described in the space group Pnma, which has the same systematic absence conditions. The long inner-cluster C—C distance of 1.510 (5) Å is typical for {1,2-Me(2)-closo-1,2-C(2)B(10)} derivatives.
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spelling pubmed-30068142010-12-30 9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca­borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9)) Finze, Maik Reiss, Guido J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(6)H(16)B(10), contains one mol­ecule that is close to possessing a non-crystallographic plane of mirror symmetry in the space group Pna2(1). The orientation of the mol­ecules in the ortho­rhom­bic cell shows that the structure can not be described in the space group Pnma, which has the same systematic absence conditions. The long inner-cluster C—C distance of 1.510 (5) Å is typical for {1,2-Me(2)-closo-1,2-C(2)B(10)} derivatives. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3006814/ /pubmed/21587928 http://dx.doi.org/10.1107/S1600536810022440 Text en © Finze and Reiss 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Finze, Maik
Reiss, Guido J.
9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca­borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9))
title 9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca­borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9))
title_full 9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca­borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9))
title_fullStr 9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca­borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9))
title_full_unstemmed 9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca­borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9))
title_short 9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca­borane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9))
title_sort 9-ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodeca­borane (1,2-me(2)-9-hc c-closo-1,2-c(2)b(10)h(9))
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006814/
https://www.ncbi.nlm.nih.gov/pubmed/21587928
http://dx.doi.org/10.1107/S1600536810022440
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AT reissguidoj 9ethynyl12dimethyl12dicarbaclosododecaborane12me29hcccloso12c2b10h9

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