2-Oxo-4-trifluoro­meth­yl-2H-chromen-7-yl 2-bromo-2-methyl­propano­ate

In the title compound, C(14)H(10)BrF(3)O(4), the coumarin ring system is almost plannar (r.m.s. deviation = 0.025 Å) and a short C—H⋯F contact occurs. The propano­ate fragment is orientated almost perpendicular to the ring [dihedral angle = 71.80 (12)°]. In the crystal, mol­ecules are linked by C—H⋯...

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Detalles Bibliográficos
Autores principales: Haridharan, N., Ramkumar, V., Dhamodharan, R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006816/
https://www.ncbi.nlm.nih.gov/pubmed/21587840
http://dx.doi.org/10.1107/S1600536810020234
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author Haridharan, N.
Ramkumar, V.
Dhamodharan, R.
author_facet Haridharan, N.
Ramkumar, V.
Dhamodharan, R.
author_sort Haridharan, N.
collection PubMed
description In the title compound, C(14)H(10)BrF(3)O(4), the coumarin ring system is almost plannar (r.m.s. deviation = 0.025 Å) and a short C—H⋯F contact occurs. The propano­ate fragment is orientated almost perpendicular to the ring [dihedral angle = 71.80 (12)°]. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, generating [100] chains.
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spelling pubmed-30068162010-12-30 2-Oxo-4-trifluoro­meth­yl-2H-chromen-7-yl 2-bromo-2-methyl­propano­ate Haridharan, N. Ramkumar, V. Dhamodharan, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(10)BrF(3)O(4), the coumarin ring system is almost plannar (r.m.s. deviation = 0.025 Å) and a short C—H⋯F contact occurs. The propano­ate fragment is orientated almost perpendicular to the ring [dihedral angle = 71.80 (12)°]. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, generating [100] chains. International Union of Crystallography 2010-06-09 /pmc/articles/PMC3006816/ /pubmed/21587840 http://dx.doi.org/10.1107/S1600536810020234 Text en © Haridharan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Haridharan, N.
Ramkumar, V.
Dhamodharan, R.
2-Oxo-4-trifluoro­meth­yl-2H-chromen-7-yl 2-bromo-2-methyl­propano­ate
title 2-Oxo-4-trifluoro­meth­yl-2H-chromen-7-yl 2-bromo-2-methyl­propano­ate
title_full 2-Oxo-4-trifluoro­meth­yl-2H-chromen-7-yl 2-bromo-2-methyl­propano­ate
title_fullStr 2-Oxo-4-trifluoro­meth­yl-2H-chromen-7-yl 2-bromo-2-methyl­propano­ate
title_full_unstemmed 2-Oxo-4-trifluoro­meth­yl-2H-chromen-7-yl 2-bromo-2-methyl­propano­ate
title_short 2-Oxo-4-trifluoro­meth­yl-2H-chromen-7-yl 2-bromo-2-methyl­propano­ate
title_sort 2-oxo-4-trifluoro­meth­yl-2h-chromen-7-yl 2-bromo-2-methyl­propano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006816/
https://www.ncbi.nlm.nih.gov/pubmed/21587840
http://dx.doi.org/10.1107/S1600536810020234
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AT ramkumarv 2oxo4trifluoromethyl2hchromen7yl2bromo2methylpropanoate
AT dhamodharanr 2oxo4trifluoromethyl2hchromen7yl2bromo2methylpropanoate

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