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N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methyl­idene]pyridine-4-carbohydrazide

In the title compound, C(12)H(12)N(4)O, the pyridine and pyrrole rings are inclined at an angle of 29.22 (8)° and an intra­molecular C—H⋯N inter­action geneates an S(6) ring. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, forming (010) C(7) chains. The chains are cross-linked by weak...

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Detalles Bibliográficos
Autores principales: Hussain, Abid, Tahir, M. Nawaz, Shafiq, Zahid, Yaqub, Muhammad, Mazhar, Muhammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006824/
https://www.ncbi.nlm.nih.gov/pubmed/21588075
http://dx.doi.org/10.1107/S1600536810025341
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author Hussain, Abid
Tahir, M. Nawaz
Shafiq, Zahid
Yaqub, Muhammad
Mazhar, Muhammad
author_facet Hussain, Abid
Tahir, M. Nawaz
Shafiq, Zahid
Yaqub, Muhammad
Mazhar, Muhammad
author_sort Hussain, Abid
collection PubMed
description In the title compound, C(12)H(12)N(4)O, the pyridine and pyrrole rings are inclined at an angle of 29.22 (8)° and an intra­molecular C—H⋯N inter­action geneates an S(6) ring. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, forming (010) C(7) chains. The chains are cross-linked by weak C—H⋯O inter­actions, which generate R (2) (2)(18) ring motifs within an infinite sheet. Finally, two C—H⋯π inter­actions are present, where the C—H groups are from the pyridine ring and π is the pyrrole ring.
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spelling pubmed-30068242010-12-30 N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methyl­idene]pyridine-4-carbohydrazide Hussain, Abid Tahir, M. Nawaz Shafiq, Zahid Yaqub, Muhammad Mazhar, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(12)N(4)O, the pyridine and pyrrole rings are inclined at an angle of 29.22 (8)° and an intra­molecular C—H⋯N inter­action geneates an S(6) ring. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, forming (010) C(7) chains. The chains are cross-linked by weak C—H⋯O inter­actions, which generate R (2) (2)(18) ring motifs within an infinite sheet. Finally, two C—H⋯π inter­actions are present, where the C—H groups are from the pyridine ring and π is the pyrrole ring. International Union of Crystallography 2010-06-30 /pmc/articles/PMC3006824/ /pubmed/21588075 http://dx.doi.org/10.1107/S1600536810025341 Text en © Hussain et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hussain, Abid
Tahir, M. Nawaz
Shafiq, Zahid
Yaqub, Muhammad
Mazhar, Muhammad
N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methyl­idene]pyridine-4-carbohydrazide
title N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methyl­idene]pyridine-4-carbohydrazide
title_full N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methyl­idene]pyridine-4-carbohydrazide
title_fullStr N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methyl­idene]pyridine-4-carbohydrazide
title_full_unstemmed N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methyl­idene]pyridine-4-carbohydrazide
title_short N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methyl­idene]pyridine-4-carbohydrazide
title_sort n′-[(e)-(1-methyl-1h-pyrrol-2-yl)methyl­idene]pyridine-4-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006824/
https://www.ncbi.nlm.nih.gov/pubmed/21588075
http://dx.doi.org/10.1107/S1600536810025341
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