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N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methylidene]pyridine-4-carbohydrazide
In the title compound, C(12)H(12)N(4)O, the pyridine and pyrrole rings are inclined at an angle of 29.22 (8)° and an intramolecular C—H⋯N interaction geneates an S(6) ring. In the crystal, molecules are linked by N—H⋯N hydrogen bonds, forming (010) C(7) chains. The chains are cross-linked by weak...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006824/ https://www.ncbi.nlm.nih.gov/pubmed/21588075 http://dx.doi.org/10.1107/S1600536810025341 |
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author | Hussain, Abid Tahir, M. Nawaz Shafiq, Zahid Yaqub, Muhammad Mazhar, Muhammad |
author_facet | Hussain, Abid Tahir, M. Nawaz Shafiq, Zahid Yaqub, Muhammad Mazhar, Muhammad |
author_sort | Hussain, Abid |
collection | PubMed |
description | In the title compound, C(12)H(12)N(4)O, the pyridine and pyrrole rings are inclined at an angle of 29.22 (8)° and an intramolecular C—H⋯N interaction geneates an S(6) ring. In the crystal, molecules are linked by N—H⋯N hydrogen bonds, forming (010) C(7) chains. The chains are cross-linked by weak C—H⋯O interactions, which generate R (2) (2)(18) ring motifs within an infinite sheet. Finally, two C—H⋯π interactions are present, where the C—H groups are from the pyridine ring and π is the pyrrole ring. |
format | Text |
id | pubmed-3006824 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30068242010-12-30 N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methylidene]pyridine-4-carbohydrazide Hussain, Abid Tahir, M. Nawaz Shafiq, Zahid Yaqub, Muhammad Mazhar, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(12)N(4)O, the pyridine and pyrrole rings are inclined at an angle of 29.22 (8)° and an intramolecular C—H⋯N interaction geneates an S(6) ring. In the crystal, molecules are linked by N—H⋯N hydrogen bonds, forming (010) C(7) chains. The chains are cross-linked by weak C—H⋯O interactions, which generate R (2) (2)(18) ring motifs within an infinite sheet. Finally, two C—H⋯π interactions are present, where the C—H groups are from the pyridine ring and π is the pyrrole ring. International Union of Crystallography 2010-06-30 /pmc/articles/PMC3006824/ /pubmed/21588075 http://dx.doi.org/10.1107/S1600536810025341 Text en © Hussain et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hussain, Abid Tahir, M. Nawaz Shafiq, Zahid Yaqub, Muhammad Mazhar, Muhammad N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methylidene]pyridine-4-carbohydrazide |
title |
N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methylidene]pyridine-4-carbohydrazide |
title_full |
N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methylidene]pyridine-4-carbohydrazide |
title_fullStr |
N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methylidene]pyridine-4-carbohydrazide |
title_full_unstemmed |
N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methylidene]pyridine-4-carbohydrazide |
title_short |
N′-[(E)-(1-Methyl-1H-pyrrol-2-yl)methylidene]pyridine-4-carbohydrazide |
title_sort | n′-[(e)-(1-methyl-1h-pyrrol-2-yl)methylidene]pyridine-4-carbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006824/ https://www.ncbi.nlm.nih.gov/pubmed/21588075 http://dx.doi.org/10.1107/S1600536810025341 |
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