Bis[μ-(E)-N′-(4-oxido-4-phenyl­but-3-en-2-yl­idene)benzohydrazidato]bis­[pyridine­copper(II)]

In the crystal structure of the title centrosymmetric dimer, [Cu(2)(C(17)H(14)N(2)O(2))(2)(C(5)H(5)N)(2)], the Cu(II) atom has an almost perfect square-pyramidal geometry. The Cu(II) ion is coordin­ated by the NO(2) donor atoms of the hydrazide Schiff base ligand, the N atom of the pyridine group an...

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Autores principales: Hatefi, Mehdi, Sheikhshoaie, Iran, Moghadam, Majid, Mirkhani, Valiollah, Kia, Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006828/
https://www.ncbi.nlm.nih.gov/pubmed/21587671
http://dx.doi.org/10.1107/S1600536810019902
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author Hatefi, Mehdi
Sheikhshoaie, Iran
Moghadam, Majid
Mirkhani, Valiollah
Kia, Reza
author_facet Hatefi, Mehdi
Sheikhshoaie, Iran
Moghadam, Majid
Mirkhani, Valiollah
Kia, Reza
author_sort Hatefi, Mehdi
collection PubMed
description In the crystal structure of the title centrosymmetric dimer, [Cu(2)(C(17)H(14)N(2)O(2))(2)(C(5)H(5)N)(2)], the Cu(II) atom has an almost perfect square-pyramidal geometry. The Cu(II) ion is coordin­ated by the NO(2) donor atoms of the hydrazide Schiff base ligand, the N atom of the pyridine group and an O atom of the symmetry-related unit. The dihedral angles between the pyridine ring and the two phenyl rings of the ligand are 21.4 (3) and 24.0 (2)°. The mol­ecular structure is stabilized by intra­molecular C—H⋯O inter­actions.
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spelling pubmed-30068282010-12-30 Bis[μ-(E)-N′-(4-oxido-4-phenyl­but-3-en-2-yl­idene)benzohydrazidato]bis­[pyridine­copper(II)] Hatefi, Mehdi Sheikhshoaie, Iran Moghadam, Majid Mirkhani, Valiollah Kia, Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title centrosymmetric dimer, [Cu(2)(C(17)H(14)N(2)O(2))(2)(C(5)H(5)N)(2)], the Cu(II) atom has an almost perfect square-pyramidal geometry. The Cu(II) ion is coordin­ated by the NO(2) donor atoms of the hydrazide Schiff base ligand, the N atom of the pyridine group and an O atom of the symmetry-related unit. The dihedral angles between the pyridine ring and the two phenyl rings of the ligand are 21.4 (3) and 24.0 (2)°. The mol­ecular structure is stabilized by intra­molecular C—H⋯O inter­actions. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006828/ /pubmed/21587671 http://dx.doi.org/10.1107/S1600536810019902 Text en © Hatefi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hatefi, Mehdi
Sheikhshoaie, Iran
Moghadam, Majid
Mirkhani, Valiollah
Kia, Reza
Bis[μ-(E)-N′-(4-oxido-4-phenyl­but-3-en-2-yl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title Bis[μ-(E)-N′-(4-oxido-4-phenyl­but-3-en-2-yl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title_full Bis[μ-(E)-N′-(4-oxido-4-phenyl­but-3-en-2-yl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title_fullStr Bis[μ-(E)-N′-(4-oxido-4-phenyl­but-3-en-2-yl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title_full_unstemmed Bis[μ-(E)-N′-(4-oxido-4-phenyl­but-3-en-2-yl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title_short Bis[μ-(E)-N′-(4-oxido-4-phenyl­but-3-en-2-yl­idene)benzohydrazidato]bis­[pyridine­copper(II)]
title_sort bis[μ-(e)-n′-(4-oxido-4-phenyl­but-3-en-2-yl­idene)benzohydrazidato]bis­[pyridine­copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006828/
https://www.ncbi.nlm.nih.gov/pubmed/21587671
http://dx.doi.org/10.1107/S1600536810019902
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