fac-Tris(4-amino­benzohydroxamato)iron(III) ethanol solvate

In the structure of the title compound, [Fe(C(7)H(7)N(2)O(2))(3)]·CH(3)CH(2)OH, the Fe(III) atom is in a distorted octa­hedral O(6) environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The m...

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Detalles Bibliográficos
Autores principales: Alagha, Ahmed B. M., Gaynor, Declan, Müller-Bunz, Helge, Nolan, Kevin B., Parthasarathi, Laavanya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006831/
https://www.ncbi.nlm.nih.gov/pubmed/21587762
http://dx.doi.org/10.1107/S160053681002413X
Descripción
Sumario:In the structure of the title compound, [Fe(C(7)H(7)N(2)O(2))(3)]·CH(3)CH(2)OH, the Fe(III) atom is in a distorted octa­hedral O(6) environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The methyl C atom of the ethanol solvent mol­ecule is disordered over two positions with occupancies of 0.626 (13) and 0.374 (13), respectively. The cocrystallized ethanol mol­ecule is hydrogen bonded to one of the hydroxamate O atoms. O—H⋯O and N—H⋯O inter­actions generate infinite three-dimensional networks along [100], [010] and [001].

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