fac-Tris(4-amino­benzohydroxamato)iron(III) ethanol solvate

In the structure of the title compound, [Fe(C(7)H(7)N(2)O(2))(3)]·CH(3)CH(2)OH, the Fe(III) atom is in a distorted octa­hedral O(6) environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The m...

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Autores principales: Alagha, Ahmed B. M., Gaynor, Declan, Müller-Bunz, Helge, Nolan, Kevin B., Parthasarathi, Laavanya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006831/
https://www.ncbi.nlm.nih.gov/pubmed/21587762
http://dx.doi.org/10.1107/S160053681002413X
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author Alagha, Ahmed B. M.
Gaynor, Declan
Müller-Bunz, Helge
Nolan, Kevin B.
Parthasarathi, Laavanya
author_facet Alagha, Ahmed B. M.
Gaynor, Declan
Müller-Bunz, Helge
Nolan, Kevin B.
Parthasarathi, Laavanya
author_sort Alagha, Ahmed B. M.
collection PubMed
description In the structure of the title compound, [Fe(C(7)H(7)N(2)O(2))(3)]·CH(3)CH(2)OH, the Fe(III) atom is in a distorted octa­hedral O(6) environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The methyl C atom of the ethanol solvent mol­ecule is disordered over two positions with occupancies of 0.626 (13) and 0.374 (13), respectively. The cocrystallized ethanol mol­ecule is hydrogen bonded to one of the hydroxamate O atoms. O—H⋯O and N—H⋯O inter­actions generate infinite three-dimensional networks along [100], [010] and [001].
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spelling pubmed-30068312010-12-30 fac-Tris(4-amino­benzohydroxamato)iron(III) ethanol solvate Alagha, Ahmed B. M. Gaynor, Declan Müller-Bunz, Helge Nolan, Kevin B. Parthasarathi, Laavanya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Fe(C(7)H(7)N(2)O(2))(3)]·CH(3)CH(2)OH, the Fe(III) atom is in a distorted octa­hedral O(6) environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The methyl C atom of the ethanol solvent mol­ecule is disordered over two positions with occupancies of 0.626 (13) and 0.374 (13), respectively. The cocrystallized ethanol mol­ecule is hydrogen bonded to one of the hydroxamate O atoms. O—H⋯O and N—H⋯O inter­actions generate infinite three-dimensional networks along [100], [010] and [001]. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006831/ /pubmed/21587762 http://dx.doi.org/10.1107/S160053681002413X Text en © Alagha et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Alagha, Ahmed B. M.
Gaynor, Declan
Müller-Bunz, Helge
Nolan, Kevin B.
Parthasarathi, Laavanya
fac-Tris(4-amino­benzohydroxamato)iron(III) ethanol solvate
title fac-Tris(4-amino­benzohydroxamato)iron(III) ethanol solvate
title_full fac-Tris(4-amino­benzohydroxamato)iron(III) ethanol solvate
title_fullStr fac-Tris(4-amino­benzohydroxamato)iron(III) ethanol solvate
title_full_unstemmed fac-Tris(4-amino­benzohydroxamato)iron(III) ethanol solvate
title_short fac-Tris(4-amino­benzohydroxamato)iron(III) ethanol solvate
title_sort fac-tris(4-amino­benzohydroxamato)iron(iii) ethanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006831/
https://www.ncbi.nlm.nih.gov/pubmed/21587762
http://dx.doi.org/10.1107/S160053681002413X
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