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1,3,5,7-Tetrakis(4-iodophenyl)adamantane benzene tetrasolvate
The title molecule, C(34)H(28)I(4)·4C(6)H(6), has crystallographic [Image: see text] symmetry and crystallizes with four symmetry-related benzene solvent molecules. The phenyl group is eclipsed with one of the adamantane C—C bonds. The tetraphenyladamantane units and the benzene solvent molecul...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006832/ https://www.ncbi.nlm.nih.gov/pubmed/21587865 http://dx.doi.org/10.1107/S1600536810021744 |
Sumario: | The title molecule, C(34)H(28)I(4)·4C(6)H(6), has crystallographic [Image: see text] symmetry and crystallizes with four symmetry-related benzene solvent molecules. The phenyl group is eclipsed with one of the adamantane C—C bonds. The tetraphenyladamantane units and the benzene solvent molecules are connected by weak intermolecular phenyl–benzene C—H⋯π and benzene–benzene C—H⋯π interactions. In the crystal, molecules are linked along the c-axis direction via the iodophenyl groups by a combination of weak intermolecular I⋯I [3.944 (1) Å] and I⋯π(phenyl) [3.608 (6) and 3.692 (5) Å] interactions. |
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