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1,3,5,7-Tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate

The title mol­ecule, C(34)H(28)I(4)·4C(6)H(6), has crystallographic [Image: see text] symmetry and crystallizes with four symmetry-related benzene solvent mol­ecules. The phenyl group is eclipsed with one of the adamantane C—C bonds. The tetra­phenyl­adamantane units and the benzene solvent mol­ecul...

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Detalles Bibliográficos
Autores principales: Bats, Jan W., Pospiech, Steffen, Prisner, Thomas F.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006832/
https://www.ncbi.nlm.nih.gov/pubmed/21587865
http://dx.doi.org/10.1107/S1600536810021744
Descripción
Sumario:The title mol­ecule, C(34)H(28)I(4)·4C(6)H(6), has crystallographic [Image: see text] symmetry and crystallizes with four symmetry-related benzene solvent mol­ecules. The phenyl group is eclipsed with one of the adamantane C—C bonds. The tetra­phenyl­adamantane units and the benzene solvent mol­ecules are connected by weak inter­molecular phen­yl–benzene C—H⋯π and benzene–benzene C—H⋯π inter­actions. In the crystal, mol­ecules are linked along the c-axis direction via the iodo­phenyl groups by a combination of weak inter­molecular I⋯I [3.944 (1) Å] and I⋯π(phen­yl) [3.608 (6) and 3.692 (5) Å] inter­actions.