1,3,5,7-Tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate

The title mol­ecule, C(34)H(28)I(4)·4C(6)H(6), has crystallographic [Image: see text] symmetry and crystallizes with four symmetry-related benzene solvent mol­ecules. The phenyl group is eclipsed with one of the adamantane C—C bonds. The tetra­phenyl­adamantane units and the benzene solvent mol­ecul...

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Detalles Bibliográficos
Autores principales: Bats, Jan W., Pospiech, Steffen, Prisner, Thomas F.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006832/
https://www.ncbi.nlm.nih.gov/pubmed/21587865
http://dx.doi.org/10.1107/S1600536810021744
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author Bats, Jan W.
Pospiech, Steffen
Prisner, Thomas F.
author_facet Bats, Jan W.
Pospiech, Steffen
Prisner, Thomas F.
author_sort Bats, Jan W.
collection PubMed
description The title mol­ecule, C(34)H(28)I(4)·4C(6)H(6), has crystallographic [Image: see text] symmetry and crystallizes with four symmetry-related benzene solvent mol­ecules. The phenyl group is eclipsed with one of the adamantane C—C bonds. The tetra­phenyl­adamantane units and the benzene solvent mol­ecules are connected by weak inter­molecular phen­yl–benzene C—H⋯π and benzene–benzene C—H⋯π inter­actions. In the crystal, mol­ecules are linked along the c-axis direction via the iodo­phenyl groups by a combination of weak inter­molecular I⋯I [3.944 (1) Å] and I⋯π(phen­yl) [3.608 (6) and 3.692 (5) Å] inter­actions.
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spelling pubmed-30068322010-12-30 1,3,5,7-Tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate Bats, Jan W. Pospiech, Steffen Prisner, Thomas F. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(34)H(28)I(4)·4C(6)H(6), has crystallographic [Image: see text] symmetry and crystallizes with four symmetry-related benzene solvent mol­ecules. The phenyl group is eclipsed with one of the adamantane C—C bonds. The tetra­phenyl­adamantane units and the benzene solvent mol­ecules are connected by weak inter­molecular phen­yl–benzene C—H⋯π and benzene–benzene C—H⋯π inter­actions. In the crystal, mol­ecules are linked along the c-axis direction via the iodo­phenyl groups by a combination of weak inter­molecular I⋯I [3.944 (1) Å] and I⋯π(phen­yl) [3.608 (6) and 3.692 (5) Å] inter­actions. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006832/ /pubmed/21587865 http://dx.doi.org/10.1107/S1600536810021744 Text en © Bats et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bats, Jan W.
Pospiech, Steffen
Prisner, Thomas F.
1,3,5,7-Tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate
title 1,3,5,7-Tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate
title_full 1,3,5,7-Tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate
title_fullStr 1,3,5,7-Tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate
title_full_unstemmed 1,3,5,7-Tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate
title_short 1,3,5,7-Tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate
title_sort 1,3,5,7-tetra­kis(4-iodo­phen­yl)adamantane benzene tetra­solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006832/
https://www.ncbi.nlm.nih.gov/pubmed/21587865
http://dx.doi.org/10.1107/S1600536810021744
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