Cargando…

Diiodido[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II)

The Cu(II) atom in the title compound, [CuI(2)(C(20)H(14)N(4))], has a distorted square-pyramidal coordination formed by the N atoms of the tridentate 4′-(4-pyrid­yl)-2,2′:6′2′′-terpyridine (pyterpy) ligand and two I atoms; one of the I atoms is in the apical position. In contrast to other known squ...

Descripción completa

Detalles Bibliográficos
Autor principal: Chen, Feng-Tao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006846/
https://www.ncbi.nlm.nih.gov/pubmed/21587691
http://dx.doi.org/10.1107/S1600536810020635
Descripción
Sumario:The Cu(II) atom in the title compound, [CuI(2)(C(20)H(14)N(4))], has a distorted square-pyramidal coordination formed by the N atoms of the tridentate 4′-(4-pyrid­yl)-2,2′:6′2′′-terpyridine (pyterpy) ligand and two I atoms; one of the I atoms is in the apical position. In contrast to other known square-pyramidal diiodido- and dibromidocopper complexes of the pyterpy ligand in which metal–halogen distances are significantly different, in the title compound the apical and equatorial Cu—I bonds are almost identical [2.6141 (8) and 2.6025 (8) Å, respectively].