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Diiodido[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II)

The Cu(II) atom in the title compound, [CuI(2)(C(20)H(14)N(4))], has a distorted square-pyramidal coordination formed by the N atoms of the tridentate 4′-(4-pyrid­yl)-2,2′:6′2′′-terpyridine (pyterpy) ligand and two I atoms; one of the I atoms is in the apical position. In contrast to other known squ...

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Autor principal: Chen, Feng-Tao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006846/
https://www.ncbi.nlm.nih.gov/pubmed/21587691
http://dx.doi.org/10.1107/S1600536810020635
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author Chen, Feng-Tao
author_facet Chen, Feng-Tao
author_sort Chen, Feng-Tao
collection PubMed
description The Cu(II) atom in the title compound, [CuI(2)(C(20)H(14)N(4))], has a distorted square-pyramidal coordination formed by the N atoms of the tridentate 4′-(4-pyrid­yl)-2,2′:6′2′′-terpyridine (pyterpy) ligand and two I atoms; one of the I atoms is in the apical position. In contrast to other known square-pyramidal diiodido- and dibromidocopper complexes of the pyterpy ligand in which metal–halogen distances are significantly different, in the title compound the apical and equatorial Cu—I bonds are almost identical [2.6141 (8) and 2.6025 (8) Å, respectively].
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spelling pubmed-30068462010-12-30 Diiodido[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II) Chen, Feng-Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title compound, [CuI(2)(C(20)H(14)N(4))], has a distorted square-pyramidal coordination formed by the N atoms of the tridentate 4′-(4-pyrid­yl)-2,2′:6′2′′-terpyridine (pyterpy) ligand and two I atoms; one of the I atoms is in the apical position. In contrast to other known square-pyramidal diiodido- and dibromidocopper complexes of the pyterpy ligand in which metal–halogen distances are significantly different, in the title compound the apical and equatorial Cu—I bonds are almost identical [2.6141 (8) and 2.6025 (8) Å, respectively]. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006846/ /pubmed/21587691 http://dx.doi.org/10.1107/S1600536810020635 Text en © Feng-Tao Chen 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Feng-Tao
Diiodido[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II)
title Diiodido[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II)
title_full Diiodido[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II)
title_fullStr Diiodido[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II)
title_full_unstemmed Diiodido[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II)
title_short Diiodido[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II)
title_sort diiodido[4′-(4-pyrid­yl)-2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006846/
https://www.ncbi.nlm.nih.gov/pubmed/21587691
http://dx.doi.org/10.1107/S1600536810020635
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