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Diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II)
The Cu(II) atom in the title compound, [CuI(2)(C(20)H(14)N(4))], has a distorted square-pyramidal coordination formed by the N atoms of the tridentate 4′-(4-pyridyl)-2,2′:6′2′′-terpyridine (pyterpy) ligand and two I atoms; one of the I atoms is in the apical position. In contrast to other known squ...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006846/ https://www.ncbi.nlm.nih.gov/pubmed/21587691 http://dx.doi.org/10.1107/S1600536810020635 |
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author | Chen, Feng-Tao |
author_facet | Chen, Feng-Tao |
author_sort | Chen, Feng-Tao |
collection | PubMed |
description | The Cu(II) atom in the title compound, [CuI(2)(C(20)H(14)N(4))], has a distorted square-pyramidal coordination formed by the N atoms of the tridentate 4′-(4-pyridyl)-2,2′:6′2′′-terpyridine (pyterpy) ligand and two I atoms; one of the I atoms is in the apical position. In contrast to other known square-pyramidal diiodido- and dibromidocopper complexes of the pyterpy ligand in which metal–halogen distances are significantly different, in the title compound the apical and equatorial Cu—I bonds are almost identical [2.6141 (8) and 2.6025 (8) Å, respectively]. |
format | Text |
id | pubmed-3006846 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30068462010-12-30 Diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II) Chen, Feng-Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title compound, [CuI(2)(C(20)H(14)N(4))], has a distorted square-pyramidal coordination formed by the N atoms of the tridentate 4′-(4-pyridyl)-2,2′:6′2′′-terpyridine (pyterpy) ligand and two I atoms; one of the I atoms is in the apical position. In contrast to other known square-pyramidal diiodido- and dibromidocopper complexes of the pyterpy ligand in which metal–halogen distances are significantly different, in the title compound the apical and equatorial Cu—I bonds are almost identical [2.6141 (8) and 2.6025 (8) Å, respectively]. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006846/ /pubmed/21587691 http://dx.doi.org/10.1107/S1600536810020635 Text en © Feng-Tao Chen 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Feng-Tao Diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′]copper(II) |
title | Diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′]copper(II) |
title_full | Diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′]copper(II) |
title_fullStr | Diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′]copper(II) |
title_full_unstemmed | Diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′]copper(II) |
title_short | Diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′]copper(II) |
title_sort | diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006846/ https://www.ncbi.nlm.nih.gov/pubmed/21587691 http://dx.doi.org/10.1107/S1600536810020635 |
work_keys_str_mv | AT chenfengtao diiodido44pyridyl2262terpyridinek3nnncopperii |