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Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate
In the title compound, C(20)H(18)Cl(2)N(4)O(8), the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, intermolecular C—H⋯N hydrogen bonds link neighbouring molecules into a ribbon-like structure alon...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006847/ https://www.ncbi.nlm.nih.gov/pubmed/21588066 http://dx.doi.org/10.1107/S1600536810024785 |
Sumario: | In the title compound, C(20)H(18)Cl(2)N(4)O(8), the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, intermolecular C—H⋯N hydrogen bonds link neighbouring molecules into a ribbon-like structure along the b axis. The ribbons are interconnected into a two-dimensional network parallel to the bc plane by short intermolecular Cl⋯Cl [3.4427 (6) Å] and Cl⋯O [3.1420 (9) and 3.1750 (11) Å] interactions. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance 3.4552 (8) Å] involving the pyrimidine rings. |
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