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Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate
In the title compound, C(20)H(18)Cl(2)N(4)O(8), the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, intermolecular C—H⋯N hydrogen bonds link neighbouring molecules into a ribbon-like structure alon...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006847/ https://www.ncbi.nlm.nih.gov/pubmed/21588066 http://dx.doi.org/10.1107/S1600536810024785 |
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author | Fun, Hoong-Kun Goh, Jia Hao Rai, Sankappa Isloor, Arun M. Shetty, Prakash |
author_facet | Fun, Hoong-Kun Goh, Jia Hao Rai, Sankappa Isloor, Arun M. Shetty, Prakash |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title compound, C(20)H(18)Cl(2)N(4)O(8), the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, intermolecular C—H⋯N hydrogen bonds link neighbouring molecules into a ribbon-like structure along the b axis. The ribbons are interconnected into a two-dimensional network parallel to the bc plane by short intermolecular Cl⋯Cl [3.4427 (6) Å] and Cl⋯O [3.1420 (9) and 3.1750 (11) Å] interactions. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance 3.4552 (8) Å] involving the pyrimidine rings. |
format | Text |
id | pubmed-3006847 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30068472010-12-30 Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate Fun, Hoong-Kun Goh, Jia Hao Rai, Sankappa Isloor, Arun M. Shetty, Prakash Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(18)Cl(2)N(4)O(8), the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, intermolecular C—H⋯N hydrogen bonds link neighbouring molecules into a ribbon-like structure along the b axis. The ribbons are interconnected into a two-dimensional network parallel to the bc plane by short intermolecular Cl⋯Cl [3.4427 (6) Å] and Cl⋯O [3.1420 (9) and 3.1750 (11) Å] interactions. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance 3.4552 (8) Å] involving the pyrimidine rings. International Union of Crystallography 2010-06-30 /pmc/articles/PMC3006847/ /pubmed/21588066 http://dx.doi.org/10.1107/S1600536810024785 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Goh, Jia Hao Rai, Sankappa Isloor, Arun M. Shetty, Prakash Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate |
title | Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate |
title_full | Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate |
title_fullStr | Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate |
title_full_unstemmed | Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate |
title_short | Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate |
title_sort | methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006847/ https://www.ncbi.nlm.nih.gov/pubmed/21588066 http://dx.doi.org/10.1107/S1600536810024785 |
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