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Methyl 2,6-bis­[(5-chloro-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate

In the title compound, C(20)H(18)Cl(2)N(4)O(8), the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, inter­molecular C—H⋯N hydrogen bonds link neighbouring mol­ecules into a ribbon-like structure alon...

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Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Rai, Sankappa, Isloor, Arun M., Shetty, Prakash
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006847/
https://www.ncbi.nlm.nih.gov/pubmed/21588066
http://dx.doi.org/10.1107/S1600536810024785
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author Fun, Hoong-Kun
Goh, Jia Hao
Rai, Sankappa
Isloor, Arun M.
Shetty, Prakash
author_facet Fun, Hoong-Kun
Goh, Jia Hao
Rai, Sankappa
Isloor, Arun M.
Shetty, Prakash
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(20)H(18)Cl(2)N(4)O(8), the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, inter­molecular C—H⋯N hydrogen bonds link neighbouring mol­ecules into a ribbon-like structure along the b axis. The ribbons are inter­connected into a two-dimensional network parallel to the bc plane by short inter­molecular Cl⋯Cl [3.4427 (6) Å] and Cl⋯O [3.1420 (9) and 3.1750 (11) Å] inter­actions. The crystal structure is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance 3.4552 (8) Å] involving the pyrimidine rings.
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spelling pubmed-30068472010-12-30 Methyl 2,6-bis­[(5-chloro-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate Fun, Hoong-Kun Goh, Jia Hao Rai, Sankappa Isloor, Arun M. Shetty, Prakash Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(18)Cl(2)N(4)O(8), the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, inter­molecular C—H⋯N hydrogen bonds link neighbouring mol­ecules into a ribbon-like structure along the b axis. The ribbons are inter­connected into a two-dimensional network parallel to the bc plane by short inter­molecular Cl⋯Cl [3.4427 (6) Å] and Cl⋯O [3.1420 (9) and 3.1750 (11) Å] inter­actions. The crystal structure is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance 3.4552 (8) Å] involving the pyrimidine rings. International Union of Crystallography 2010-06-30 /pmc/articles/PMC3006847/ /pubmed/21588066 http://dx.doi.org/10.1107/S1600536810024785 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Goh, Jia Hao
Rai, Sankappa
Isloor, Arun M.
Shetty, Prakash
Methyl 2,6-bis­[(5-chloro-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title Methyl 2,6-bis­[(5-chloro-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title_full Methyl 2,6-bis­[(5-chloro-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title_fullStr Methyl 2,6-bis­[(5-chloro-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title_full_unstemmed Methyl 2,6-bis­[(5-chloro-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title_short Methyl 2,6-bis­[(5-chloro-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title_sort methyl 2,6-bis­[(5-chloro-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006847/
https://www.ncbi.nlm.nih.gov/pubmed/21588066
http://dx.doi.org/10.1107/S1600536810024785
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