Bis(nitrato-κO)(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-6,13-diaminium-κ(4) N (1),N (4),N (8),N (11))copper(II) dinitrate tetra­hydrate

In the title compound, [Cu(NO(3))(2)(C(14)H(36)N(6))](NO(3))(2)·4H(2)O, the Cu(II) atom, lying on an inversion center, is six-coordinated in a distorted octa­hedral environment by four N atoms from a centrosymmetric 14-membered tetra­aza­cyclo­tetra­decane macrocyclic ligand and two O atoms from two...

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Detalles Bibliográficos
Autores principales: Liu, Xiang-Yun, Chu, Hong-Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006849/
https://www.ncbi.nlm.nih.gov/pubmed/21587749
http://dx.doi.org/10.1107/S1600536810023342
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author Liu, Xiang-Yun
Chu, Hong-Ying
author_facet Liu, Xiang-Yun
Chu, Hong-Ying
author_sort Liu, Xiang-Yun
collection PubMed
description In the title compound, [Cu(NO(3))(2)(C(14)H(36)N(6))](NO(3))(2)·4H(2)O, the Cu(II) atom, lying on an inversion center, is six-coordinated in a distorted octa­hedral environment by four N atoms from a centrosymmetric 14-membered tetra­aza­cyclo­tetra­decane macrocyclic ligand and two O atoms from two nitrate anions. The supra­molecular network is consolidated by extensive O—H⋯O and N—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-30068492010-12-30 Bis(nitrato-κO)(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-6,13-diaminium-κ(4) N (1),N (4),N (8),N (11))copper(II) dinitrate tetra­hydrate Liu, Xiang-Yun Chu, Hong-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NO(3))(2)(C(14)H(36)N(6))](NO(3))(2)·4H(2)O, the Cu(II) atom, lying on an inversion center, is six-coordinated in a distorted octa­hedral environment by four N atoms from a centrosymmetric 14-membered tetra­aza­cyclo­tetra­decane macrocyclic ligand and two O atoms from two nitrate anions. The supra­molecular network is consolidated by extensive O—H⋯O and N—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2010-06-23 /pmc/articles/PMC3006849/ /pubmed/21587749 http://dx.doi.org/10.1107/S1600536810023342 Text en © Liu and Chu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Xiang-Yun
Chu, Hong-Ying
Bis(nitrato-κO)(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-6,13-diaminium-κ(4) N (1),N (4),N (8),N (11))copper(II) dinitrate tetra­hydrate
title Bis(nitrato-κO)(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-6,13-diaminium-κ(4) N (1),N (4),N (8),N (11))copper(II) dinitrate tetra­hydrate
title_full Bis(nitrato-κO)(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-6,13-diaminium-κ(4) N (1),N (4),N (8),N (11))copper(II) dinitrate tetra­hydrate
title_fullStr Bis(nitrato-κO)(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-6,13-diaminium-κ(4) N (1),N (4),N (8),N (11))copper(II) dinitrate tetra­hydrate
title_full_unstemmed Bis(nitrato-κO)(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-6,13-diaminium-κ(4) N (1),N (4),N (8),N (11))copper(II) dinitrate tetra­hydrate
title_short Bis(nitrato-κO)(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-6,13-diaminium-κ(4) N (1),N (4),N (8),N (11))copper(II) dinitrate tetra­hydrate
title_sort bis(nitrato-κo)(5,7,12,14-tetra­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane-6,13-diaminium-κ(4) n (1),n (4),n (8),n (11))copper(ii) dinitrate tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006849/
https://www.ncbi.nlm.nih.gov/pubmed/21587749
http://dx.doi.org/10.1107/S1600536810023342
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AT chuhongying bisnitratoko571214tetramethyl14811tetraazacyclotetradecane613diaminiumk4n1n4n8n11copperiidinitratetetrahydrate

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