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Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate

The title complex, [Nd(C(6)H(6)NO(3)S)(2)(C(12)H(8)N(2))(2)(H(2)O)(3)]NO(3)·4H(2)O, comprises a mononuclear cation, an NO(3) (−) anion and two uncoordinated water mol­ecules; the Nd(III) cation, one coordinated water mol­ecule, and the NO(3) (−) anion each lie on a twofold axis of symmetry. The Nd(I...

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Detalles Bibliográficos
Autores principales: Ma, Peng, Huang, Miao-Ling, Chen, Kai-Han
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006851/
https://www.ncbi.nlm.nih.gov/pubmed/21587746
http://dx.doi.org/10.1107/S1600536810023445
Descripción
Sumario:The title complex, [Nd(C(6)H(6)NO(3)S)(2)(C(12)H(8)N(2))(2)(H(2)O)(3)]NO(3)·4H(2)O, comprises a mononuclear cation, an NO(3) (−) anion and two uncoordinated water mol­ecules; the Nd(III) cation, one coordinated water mol­ecule, and the NO(3) (−) anion each lie on a twofold axis of symmetry. The Nd(III) ion exhibits an NdN(4)O(5) coordination environment comprising two O atoms of two monodentate 4-amino­benzene­sulfonato ligands, four N atoms of the bidentate 1,10-phenanthroline ligands, and three water-O atoms. The coordination geometry is based on a tricapped triangular-prismatic arrangement. The components are consolidated into a three-dimensional network via O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding inter­actions