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Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
The title complex, [Nd(C(6)H(6)NO(3)S)(2)(C(12)H(8)N(2))(2)(H(2)O)(3)]NO(3)·4H(2)O, comprises a mononuclear cation, an NO(3) (−) anion and two uncoordinated water molecules; the Nd(III) cation, one coordinated water molecule, and the NO(3) (−) anion each lie on a twofold axis of symmetry. The Nd(I...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006851/ https://www.ncbi.nlm.nih.gov/pubmed/21587746 http://dx.doi.org/10.1107/S1600536810023445 |
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author | Ma, Peng Huang, Miao-Ling Chen, Kai-Han |
author_facet | Ma, Peng Huang, Miao-Ling Chen, Kai-Han |
author_sort | Ma, Peng |
collection | PubMed |
description | The title complex, [Nd(C(6)H(6)NO(3)S)(2)(C(12)H(8)N(2))(2)(H(2)O)(3)]NO(3)·4H(2)O, comprises a mononuclear cation, an NO(3) (−) anion and two uncoordinated water molecules; the Nd(III) cation, one coordinated water molecule, and the NO(3) (−) anion each lie on a twofold axis of symmetry. The Nd(III) ion exhibits an NdN(4)O(5) coordination environment comprising two O atoms of two monodentate 4-aminobenzenesulfonato ligands, four N atoms of the bidentate 1,10-phenanthroline ligands, and three water-O atoms. The coordination geometry is based on a tricapped triangular-prismatic arrangement. The components are consolidated into a three-dimensional network via O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding interactions |
format | Text |
id | pubmed-3006851 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30068512010-12-30 Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate Ma, Peng Huang, Miao-Ling Chen, Kai-Han Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Nd(C(6)H(6)NO(3)S)(2)(C(12)H(8)N(2))(2)(H(2)O)(3)]NO(3)·4H(2)O, comprises a mononuclear cation, an NO(3) (−) anion and two uncoordinated water molecules; the Nd(III) cation, one coordinated water molecule, and the NO(3) (−) anion each lie on a twofold axis of symmetry. The Nd(III) ion exhibits an NdN(4)O(5) coordination environment comprising two O atoms of two monodentate 4-aminobenzenesulfonato ligands, four N atoms of the bidentate 1,10-phenanthroline ligands, and three water-O atoms. The coordination geometry is based on a tricapped triangular-prismatic arrangement. The components are consolidated into a three-dimensional network via O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding interactions International Union of Crystallography 2010-06-23 /pmc/articles/PMC3006851/ /pubmed/21587746 http://dx.doi.org/10.1107/S1600536810023445 Text en © Ma et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ma, Peng Huang, Miao-Ling Chen, Kai-Han Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate |
title | Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate |
title_full | Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate |
title_fullStr | Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate |
title_full_unstemmed | Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate |
title_short | Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate |
title_sort | bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(iii) nitrate tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006851/ https://www.ncbi.nlm.nih.gov/pubmed/21587746 http://dx.doi.org/10.1107/S1600536810023445 |
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