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Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate

The title complex, [Nd(C(6)H(6)NO(3)S)(2)(C(12)H(8)N(2))(2)(H(2)O)(3)]NO(3)·4H(2)O, comprises a mononuclear cation, an NO(3) (−) anion and two uncoordinated water mol­ecules; the Nd(III) cation, one coordinated water mol­ecule, and the NO(3) (−) anion each lie on a twofold axis of symmetry. The Nd(I...

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Detalles Bibliográficos
Autores principales: Ma, Peng, Huang, Miao-Ling, Chen, Kai-Han
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006851/
https://www.ncbi.nlm.nih.gov/pubmed/21587746
http://dx.doi.org/10.1107/S1600536810023445
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author Ma, Peng
Huang, Miao-Ling
Chen, Kai-Han
author_facet Ma, Peng
Huang, Miao-Ling
Chen, Kai-Han
author_sort Ma, Peng
collection PubMed
description The title complex, [Nd(C(6)H(6)NO(3)S)(2)(C(12)H(8)N(2))(2)(H(2)O)(3)]NO(3)·4H(2)O, comprises a mononuclear cation, an NO(3) (−) anion and two uncoordinated water mol­ecules; the Nd(III) cation, one coordinated water mol­ecule, and the NO(3) (−) anion each lie on a twofold axis of symmetry. The Nd(III) ion exhibits an NdN(4)O(5) coordination environment comprising two O atoms of two monodentate 4-amino­benzene­sulfonato ligands, four N atoms of the bidentate 1,10-phenanthroline ligands, and three water-O atoms. The coordination geometry is based on a tricapped triangular-prismatic arrangement. The components are consolidated into a three-dimensional network via O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding inter­actions
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spelling pubmed-30068512010-12-30 Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate Ma, Peng Huang, Miao-Ling Chen, Kai-Han Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Nd(C(6)H(6)NO(3)S)(2)(C(12)H(8)N(2))(2)(H(2)O)(3)]NO(3)·4H(2)O, comprises a mononuclear cation, an NO(3) (−) anion and two uncoordinated water mol­ecules; the Nd(III) cation, one coordinated water mol­ecule, and the NO(3) (−) anion each lie on a twofold axis of symmetry. The Nd(III) ion exhibits an NdN(4)O(5) coordination environment comprising two O atoms of two monodentate 4-amino­benzene­sulfonato ligands, four N atoms of the bidentate 1,10-phenanthroline ligands, and three water-O atoms. The coordination geometry is based on a tricapped triangular-prismatic arrangement. The components are consolidated into a three-dimensional network via O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding inter­actions International Union of Crystallography 2010-06-23 /pmc/articles/PMC3006851/ /pubmed/21587746 http://dx.doi.org/10.1107/S1600536810023445 Text en © Ma et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Peng
Huang, Miao-Ling
Chen, Kai-Han
Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title_full Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title_fullStr Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title_full_unstemmed Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title_short Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
title_sort bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(iii) nitrate tetrahydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006851/
https://www.ncbi.nlm.nih.gov/pubmed/21587746
http://dx.doi.org/10.1107/S1600536810023445
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