Phenyl 2,3,4-tri-O-benzyl-1-thio-α-d-mannopyran­oside monohydrate

In the title compound, C(33)H(34)O(5)S·H(2)O, the mannopyran­oside ring adopts a chair conformation with the 2-α-thio­phenyl group occupying an axial position. One of the pendant benzyl groups is disordered over two sets of sites in a 0.5:0.5 ratio. In the crystal, the water mol­ecule makes two O—H⋯...

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Autores principales: Durka, Maxime, Norberg, Bernadette, Roué, Yvain, Vincent, Stéphane P., Wouters, Johan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006854/
https://www.ncbi.nlm.nih.gov/pubmed/21587775
http://dx.doi.org/10.1107/S1600536810019604
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author Durka, Maxime
Norberg, Bernadette
Roué, Yvain
Vincent, Stéphane P.
Wouters, Johan
author_facet Durka, Maxime
Norberg, Bernadette
Roué, Yvain
Vincent, Stéphane P.
Wouters, Johan
author_sort Durka, Maxime
collection PubMed
description In the title compound, C(33)H(34)O(5)S·H(2)O, the mannopyran­oside ring adopts a chair conformation with the 2-α-thio­phenyl group occupying an axial position. One of the pendant benzyl groups is disordered over two sets of sites in a 0.5:0.5 ratio. In the crystal, the water mol­ecule makes two O—H⋯O hydrogen bonds to an adjacent sugar mol­ecule with the O atoms of the primary alcohol and ether groups acting as acceptors. At the same time, the OH group of the sugar makes a hydrogen bond to a water mol­ecule.
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spelling pubmed-30068542010-12-30 Phenyl 2,3,4-tri-O-benzyl-1-thio-α-d-mannopyran­oside monohydrate Durka, Maxime Norberg, Bernadette Roué, Yvain Vincent, Stéphane P. Wouters, Johan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(33)H(34)O(5)S·H(2)O, the mannopyran­oside ring adopts a chair conformation with the 2-α-thio­phenyl group occupying an axial position. One of the pendant benzyl groups is disordered over two sets of sites in a 0.5:0.5 ratio. In the crystal, the water mol­ecule makes two O—H⋯O hydrogen bonds to an adjacent sugar mol­ecule with the O atoms of the primary alcohol and ether groups acting as acceptors. At the same time, the OH group of the sugar makes a hydrogen bond to a water mol­ecule. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006854/ /pubmed/21587775 http://dx.doi.org/10.1107/S1600536810019604 Text en © Durka et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Durka, Maxime
Norberg, Bernadette
Roué, Yvain
Vincent, Stéphane P.
Wouters, Johan
Phenyl 2,3,4-tri-O-benzyl-1-thio-α-d-mannopyran­oside monohydrate
title Phenyl 2,3,4-tri-O-benzyl-1-thio-α-d-mannopyran­oside monohydrate
title_full Phenyl 2,3,4-tri-O-benzyl-1-thio-α-d-mannopyran­oside monohydrate
title_fullStr Phenyl 2,3,4-tri-O-benzyl-1-thio-α-d-mannopyran­oside monohydrate
title_full_unstemmed Phenyl 2,3,4-tri-O-benzyl-1-thio-α-d-mannopyran­oside monohydrate
title_short Phenyl 2,3,4-tri-O-benzyl-1-thio-α-d-mannopyran­oside monohydrate
title_sort phenyl 2,3,4-tri-o-benzyl-1-thio-α-d-mannopyran­oside monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006854/
https://www.ncbi.nlm.nih.gov/pubmed/21587775
http://dx.doi.org/10.1107/S1600536810019604
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AT vincentstephanep phenyl234triobenzyl1thioadmannopyranosidemonohydrate
AT woutersjohan phenyl234triobenzyl1thioadmannopyranosidemonohydrate

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