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(4-Carboxy-2-sulfonatobenzoato-κ(2) O (1),O (2))bis(1,10-phenanthroline-κ(2) N,N′)manganese(II)
In the title complex, [Mn(C(8)H(4)O(7)S)(C(12)H(8)N(2))(2)], the Mn(II) atom is chelated by one 4-carboxy-2-sulfonatobenzoate anion and two phenathroline (phen) ligands in a distorted octahedral MnN(4)O(2) geometry. The benzene ring of the 4-carboxy-2-sulfonatobenzoate anion is twisted with res...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006856/ https://www.ncbi.nlm.nih.gov/pubmed/21587760 http://dx.doi.org/10.1107/S1600536810023743 |
| Sumario: | In the title complex, [Mn(C(8)H(4)O(7)S)(C(12)H(8)N(2))(2)], the Mn(II) atom is chelated by one 4-carboxy-2-sulfonatobenzoate anion and two phenathroline (phen) ligands in a distorted octahedral MnN(4)O(2) geometry. The benzene ring of the 4-carboxy-2-sulfonatobenzoate anion is twisted with respect to the two phen ring systems at dihedral angles of 66.38 (9) and 53.56 (9)°. In the crystal, intermolecular O—H⋯O and C—H⋯O hydrogen bonding links the molecules into chains running parallel to [100]. Intermolecular π–π stacking is also observed between parallel phen ring systems, the face-to-face distance being 3.432 (6) Å. |
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