Cargando…

(4-Carb­oxy-2-sulfonato­benzoato-κ(2) O (1),O (2))bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II)

In the title complex, [Mn(C(8)H(4)O(7)S)(C(12)H(8)N(2))(2)], the Mn(II) atom is chelated by one 4-carb­oxy-2-sulfonato­benzoate anion and two phenathroline (phen) ligands in a distorted octa­hedral MnN(4)O(2) geometry. The benzene ring of the 4-carb­oxy-2-sulfonato­benzoate anion is twisted with res...

Descripción completa

Detalles Bibliográficos
Autores principales: Wu, Qiong-Fang, Li, Ming-Xing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006856/
https://www.ncbi.nlm.nih.gov/pubmed/21587760
http://dx.doi.org/10.1107/S1600536810023743
Descripción
Sumario:In the title complex, [Mn(C(8)H(4)O(7)S)(C(12)H(8)N(2))(2)], the Mn(II) atom is chelated by one 4-carb­oxy-2-sulfonato­benzoate anion and two phenathroline (phen) ligands in a distorted octa­hedral MnN(4)O(2) geometry. The benzene ring of the 4-carb­oxy-2-sulfonato­benzoate anion is twisted with respect to the two phen ring systems at dihedral angles of 66.38 (9) and 53.56 (9)°. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonding links the mol­ecules into chains running parallel to [100]. Inter­molecular π–π stacking is also observed between parallel phen ring systems, the face-to-face distance being 3.432 (6) Å.