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(4-Carboxy-2-sulfonatobenzoato-κ(2) O (1),O (2))bis(1,10-phenanthroline-κ(2) N,N′)manganese(II)
In the title complex, [Mn(C(8)H(4)O(7)S)(C(12)H(8)N(2))(2)], the Mn(II) atom is chelated by one 4-carboxy-2-sulfonatobenzoate anion and two phenathroline (phen) ligands in a distorted octahedral MnN(4)O(2) geometry. The benzene ring of the 4-carboxy-2-sulfonatobenzoate anion is twisted with res...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006856/ https://www.ncbi.nlm.nih.gov/pubmed/21587760 http://dx.doi.org/10.1107/S1600536810023743 |
| _version_ | 1782194238781390848 |
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| author | Wu, Qiong-Fang Li, Ming-Xing |
| author_facet | Wu, Qiong-Fang Li, Ming-Xing |
| author_sort | Wu, Qiong-Fang |
| collection | PubMed |
| description | In the title complex, [Mn(C(8)H(4)O(7)S)(C(12)H(8)N(2))(2)], the Mn(II) atom is chelated by one 4-carboxy-2-sulfonatobenzoate anion and two phenathroline (phen) ligands in a distorted octahedral MnN(4)O(2) geometry. The benzene ring of the 4-carboxy-2-sulfonatobenzoate anion is twisted with respect to the two phen ring systems at dihedral angles of 66.38 (9) and 53.56 (9)°. In the crystal, intermolecular O—H⋯O and C—H⋯O hydrogen bonding links the molecules into chains running parallel to [100]. Intermolecular π–π stacking is also observed between parallel phen ring systems, the face-to-face distance being 3.432 (6) Å. |
| format | Text |
| id | pubmed-3006856 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30068562010-12-30 (4-Carboxy-2-sulfonatobenzoato-κ(2) O (1),O (2))bis(1,10-phenanthroline-κ(2) N,N′)manganese(II) Wu, Qiong-Fang Li, Ming-Xing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(8)H(4)O(7)S)(C(12)H(8)N(2))(2)], the Mn(II) atom is chelated by one 4-carboxy-2-sulfonatobenzoate anion and two phenathroline (phen) ligands in a distorted octahedral MnN(4)O(2) geometry. The benzene ring of the 4-carboxy-2-sulfonatobenzoate anion is twisted with respect to the two phen ring systems at dihedral angles of 66.38 (9) and 53.56 (9)°. In the crystal, intermolecular O—H⋯O and C—H⋯O hydrogen bonding links the molecules into chains running parallel to [100]. Intermolecular π–π stacking is also observed between parallel phen ring systems, the face-to-face distance being 3.432 (6) Å. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006856/ /pubmed/21587760 http://dx.doi.org/10.1107/S1600536810023743 Text en © Wu and Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wu, Qiong-Fang Li, Ming-Xing (4-Carboxy-2-sulfonatobenzoato-κ(2) O (1),O (2))bis(1,10-phenanthroline-κ(2) N,N′)manganese(II) |
| title | (4-Carboxy-2-sulfonatobenzoato-κ(2)
O
(1),O
(2))bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) |
| title_full | (4-Carboxy-2-sulfonatobenzoato-κ(2)
O
(1),O
(2))bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) |
| title_fullStr | (4-Carboxy-2-sulfonatobenzoato-κ(2)
O
(1),O
(2))bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) |
| title_full_unstemmed | (4-Carboxy-2-sulfonatobenzoato-κ(2)
O
(1),O
(2))bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) |
| title_short | (4-Carboxy-2-sulfonatobenzoato-κ(2)
O
(1),O
(2))bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) |
| title_sort | (4-carboxy-2-sulfonatobenzoato-κ(2)
o
(1),o
(2))bis(1,10-phenanthroline-κ(2)
n,n′)manganese(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006856/ https://www.ncbi.nlm.nih.gov/pubmed/21587760 http://dx.doi.org/10.1107/S1600536810023743 |
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