2-Chloro-4-nitro-1H-imidazole

The mol­ecule of the title compound, C(3)H(2)ClN(3)O(2), is almost planar; the dihedral angle between the imidazole ring and the nitro group is 1.7 (2)°. In the crystal structure, pairs of inter­molecular C—H⋯O hydrogen bonds link inversion-related mol­ecules into dimers, generating R (2) (2)(10) ri...

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Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Chandrakantha, B., Isloor, Arun M., Shetty, Prakash
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006860/
https://www.ncbi.nlm.nih.gov/pubmed/21588034
http://dx.doi.org/10.1107/S1600536810024542
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author Fun, Hoong-Kun
Goh, Jia Hao
Chandrakantha, B.
Isloor, Arun M.
Shetty, Prakash
author_facet Fun, Hoong-Kun
Goh, Jia Hao
Chandrakantha, B.
Isloor, Arun M.
Shetty, Prakash
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title compound, C(3)H(2)ClN(3)O(2), is almost planar; the dihedral angle between the imidazole ring and the nitro group is 1.7 (2)°. In the crystal structure, pairs of inter­molecular C—H⋯O hydrogen bonds link inversion-related mol­ecules into dimers, generating R (2) (2)(10) ring motifs. The dimers are inter­connected into two-dimensional networks parallel to (102) via inter­molecular N—H⋯N hydrogen bonds. Further stabilization is provided by short inter­molecular Cl⋯O inter­actions [3.142 (2) and 3.1475 (19) Å].
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spelling pubmed-30068602010-12-30 2-Chloro-4-nitro-1H-imidazole Fun, Hoong-Kun Goh, Jia Hao Chandrakantha, B. Isloor, Arun M. Shetty, Prakash Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(3)H(2)ClN(3)O(2), is almost planar; the dihedral angle between the imidazole ring and the nitro group is 1.7 (2)°. In the crystal structure, pairs of inter­molecular C—H⋯O hydrogen bonds link inversion-related mol­ecules into dimers, generating R (2) (2)(10) ring motifs. The dimers are inter­connected into two-dimensional networks parallel to (102) via inter­molecular N—H⋯N hydrogen bonds. Further stabilization is provided by short inter­molecular Cl⋯O inter­actions [3.142 (2) and 3.1475 (19) Å]. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006860/ /pubmed/21588034 http://dx.doi.org/10.1107/S1600536810024542 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Goh, Jia Hao
Chandrakantha, B.
Isloor, Arun M.
Shetty, Prakash
2-Chloro-4-nitro-1H-imidazole
title 2-Chloro-4-nitro-1H-imidazole
title_full 2-Chloro-4-nitro-1H-imidazole
title_fullStr 2-Chloro-4-nitro-1H-imidazole
title_full_unstemmed 2-Chloro-4-nitro-1H-imidazole
title_short 2-Chloro-4-nitro-1H-imidazole
title_sort 2-chloro-4-nitro-1h-imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006860/
https://www.ncbi.nlm.nih.gov/pubmed/21588034
http://dx.doi.org/10.1107/S1600536810024542
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AT chandrakanthab 2chloro4nitro1himidazole
AT isloorarunm 2chloro4nitro1himidazole
AT shettyprakash 2chloro4nitro1himidazole

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