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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate

In the title compound, [Cd(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cd(II) atom has a distorted octa­hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. The two chelating NCCN groups subtend a dihedral a...

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Detalles Bibliográficos
Autores principales: Zhong, Kai-Long, Cui, Jiang-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006862/
https://www.ncbi.nlm.nih.gov/pubmed/21587734
http://dx.doi.org/10.1107/S1600536810022518
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author Zhong, Kai-Long
Cui, Jiang-Dong
author_facet Zhong, Kai-Long
Cui, Jiang-Dong
author_sort Zhong, Kai-Long
collection PubMed
description In the title compound, [Cd(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cd(II) atom has a distorted octa­hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. The two chelating NCCN groups subtend a dihedral angle of 82.21 (9)°. The Cd(II) ion, the S atom and the middle C atom of the propane-1,3-diol solvent mol­ecule are located on special positions, site symmetry 2. The solvate features a pair of O—H⋯O hydrogen bonds with the uncoordinated O atoms of the sulfate ion. The OH group of the propane-1,3-diol solvent is disordered over two positions of equal occupancy.
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spelling pubmed-30068622010-12-30 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate Zhong, Kai-Long Cui, Jiang-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cd(II) atom has a distorted octa­hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. The two chelating NCCN groups subtend a dihedral angle of 82.21 (9)°. The Cd(II) ion, the S atom and the middle C atom of the propane-1,3-diol solvent mol­ecule are located on special positions, site symmetry 2. The solvate features a pair of O—H⋯O hydrogen bonds with the uncoordinated O atoms of the sulfate ion. The OH group of the propane-1,3-diol solvent is disordered over two positions of equal occupancy. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3006862/ /pubmed/21587734 http://dx.doi.org/10.1107/S1600536810022518 Text en © Zhong and Cui 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhong, Kai-Long
Cui, Jiang-Dong
Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate
title Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate
title_full Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate
title_short Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate
title_sort bis(1,10-phenanthroline-κ(2) n,n′)(sulfato-κ(2) o,o′)cadmium(ii) propane-1,3-diol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006862/
https://www.ncbi.nlm.nih.gov/pubmed/21587734
http://dx.doi.org/10.1107/S1600536810022518
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AT cuijiangdong bis110phenanthrolinek2nnsulfatok2oocadmiumiipropane13diolsolvate