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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate
In the title compound, [Cd(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cd(II) atom has a distorted octahedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. The two chelating NCCN groups subtend a dihedral a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006862/ https://www.ncbi.nlm.nih.gov/pubmed/21587734 http://dx.doi.org/10.1107/S1600536810022518 |
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author | Zhong, Kai-Long Cui, Jiang-Dong |
author_facet | Zhong, Kai-Long Cui, Jiang-Dong |
author_sort | Zhong, Kai-Long |
collection | PubMed |
description | In the title compound, [Cd(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cd(II) atom has a distorted octahedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. The two chelating NCCN groups subtend a dihedral angle of 82.21 (9)°. The Cd(II) ion, the S atom and the middle C atom of the propane-1,3-diol solvent molecule are located on special positions, site symmetry 2. The solvate features a pair of O—H⋯O hydrogen bonds with the uncoordinated O atoms of the sulfate ion. The OH group of the propane-1,3-diol solvent is disordered over two positions of equal occupancy. |
format | Text |
id | pubmed-3006862 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30068622010-12-30 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate Zhong, Kai-Long Cui, Jiang-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cd(II) atom has a distorted octahedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. The two chelating NCCN groups subtend a dihedral angle of 82.21 (9)°. The Cd(II) ion, the S atom and the middle C atom of the propane-1,3-diol solvent molecule are located on special positions, site symmetry 2. The solvate features a pair of O—H⋯O hydrogen bonds with the uncoordinated O atoms of the sulfate ion. The OH group of the propane-1,3-diol solvent is disordered over two positions of equal occupancy. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3006862/ /pubmed/21587734 http://dx.doi.org/10.1107/S1600536810022518 Text en © Zhong and Cui 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhong, Kai-Long Cui, Jiang-Dong Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-κ(2) O,O′)cadmium(II) propane-1,3-diol solvate |
title | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κ(2)
O,O′)cadmium(II) propane-1,3-diol solvate |
title_full | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κ(2)
O,O′)cadmium(II) propane-1,3-diol solvate |
title_fullStr | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κ(2)
O,O′)cadmium(II) propane-1,3-diol solvate |
title_full_unstemmed | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κ(2)
O,O′)cadmium(II) propane-1,3-diol solvate |
title_short | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-κ(2)
O,O′)cadmium(II) propane-1,3-diol solvate |
title_sort | bis(1,10-phenanthroline-κ(2)
n,n′)(sulfato-κ(2)
o,o′)cadmium(ii) propane-1,3-diol solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006862/ https://www.ncbi.nlm.nih.gov/pubmed/21587734 http://dx.doi.org/10.1107/S1600536810022518 |
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