Tetra­butyl­ammonium bis­[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ato]vanadium(III) acetonitrile tetra­solvate

In the title compound, [N(C(4)H(9))(4)][V(C(23)H(21)NS(3)Si)(2)]·4CH(3)CN, the V(III) atom (site symmetry [Image: see text]) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ate ligands in a distorted trans-VN(2)S(4) octa­...

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Autores principales: Tsai, Yi-Fang, Hsu, Hua-Fen, Hsu, Kuei-Fang, Wang, Ju-Chun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006863/
https://www.ncbi.nlm.nih.gov/pubmed/21587755
http://dx.doi.org/10.1107/S1600536810022014
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author Tsai, Yi-Fang
Hsu, Hua-Fen
Hsu, Kuei-Fang
Wang, Ju-Chun
author_facet Tsai, Yi-Fang
Hsu, Hua-Fen
Hsu, Kuei-Fang
Wang, Ju-Chun
author_sort Tsai, Yi-Fang
collection PubMed
description In the title compound, [N(C(4)H(9))(4)][V(C(23)H(21)NS(3)Si)(2)]·4CH(3)CN, the V(III) atom (site symmetry [Image: see text]) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ate ligands in a distorted trans-VN(2)S(4) octa­hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol­ate precursor and reduction of nitrile to the imidate.
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spelling pubmed-30068632010-12-30 Tetra­butyl­ammonium bis­[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ato]vanadium(III) acetonitrile tetra­solvate Tsai, Yi-Fang Hsu, Hua-Fen Hsu, Kuei-Fang Wang, Ju-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [N(C(4)H(9))(4)][V(C(23)H(21)NS(3)Si)(2)]·4CH(3)CN, the V(III) atom (site symmetry [Image: see text]) is coordinated by two N,S,S′-tridentate 4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ate ligands in a distorted trans-VN(2)S(4) octa­hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol­ate precursor and reduction of nitrile to the imidate. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006863/ /pubmed/21587755 http://dx.doi.org/10.1107/S1600536810022014 Text en © Tsai et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tsai, Yi-Fang
Hsu, Hua-Fen
Hsu, Kuei-Fang
Wang, Ju-Chun
Tetra­butyl­ammonium bis­[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ato]vanadium(III) acetonitrile tetra­solvate
title Tetra­butyl­ammonium bis­[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ato]vanadium(III) acetonitrile tetra­solvate
title_full Tetra­butyl­ammonium bis­[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ato]vanadium(III) acetonitrile tetra­solvate
title_fullStr Tetra­butyl­ammonium bis­[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ato]vanadium(III) acetonitrile tetra­solvate
title_full_unstemmed Tetra­butyl­ammonium bis­[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ato]vanadium(III) acetonitrile tetra­solvate
title_short Tetra­butyl­ammonium bis­[4,4′-dimethyl-2,2′-(3,7-dimethyl-1H-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ato]vanadium(III) acetonitrile tetra­solvate
title_sort tetra­butyl­ammonium bis­[4,4′-dimethyl-2,2′-(3,7-dimethyl-1h-4,2,1-benzothiaza­siline-1,1-di­yl)dibenzene­thiol­ato]vanadium(iii) acetonitrile tetra­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006863/
https://www.ncbi.nlm.nih.gov/pubmed/21587755
http://dx.doi.org/10.1107/S1600536810022014
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AT hsuhuafen tetrabutylammoniumbis44dimethyl2237dimethyl1h421benzothiazasiline11diyldibenzenethiolatovanadiumiiiacetonitriletetrasolvate
AT hsukueifang tetrabutylammoniumbis44dimethyl2237dimethyl1h421benzothiazasiline11diyldibenzenethiolatovanadiumiiiacetonitriletetrasolvate
AT wangjuchun tetrabutylammoniumbis44dimethyl2237dimethyl1h421benzothiazasiline11diyldibenzenethiolatovanadiumiiiacetonitriletetrasolvate

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