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(5,15-Dianthracen-9-yl-10,20-dihexylporphyrinato)nickel(II): a planar nickel(II) porphyrin
The title compound, [Ni(C(60)H(52)N(4))], is an example of a meso tetrasubstituted nickel(II) porphyrin with both meso aryl and alkyl residues. The molecule exhibits a planar macrocycle with an average deviation of the 24 macrocycle atoms from their least-squares plane (Δ24) of 0.01 Å and an avera...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006865/ https://www.ncbi.nlm.nih.gov/pubmed/21587714 http://dx.doi.org/10.1107/S1600536810021434 |
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author | Senge, Mathias O. Davis, Mia |
author_facet | Senge, Mathias O. Davis, Mia |
author_sort | Senge, Mathias O. |
collection | PubMed |
description | The title compound, [Ni(C(60)H(52)N(4))], is an example of a meso tetrasubstituted nickel(II) porphyrin with both meso aryl and alkyl residues. The molecule exhibits a planar macrocycle with an average deviation of the 24 macrocycle atoms from their least-squares plane (Δ24) of 0.01 Å and an average Ni—N bond length of 1.960 (2) Å. The Ni(II) atom lies on a center of inversion. The structure presents a rare example for a planar nickel(II) porphyrin, as meso-substituted nickel(II) porphyrins with either only meso-aryl or with meso-alkyl residues typically exhibit a ruffled conformation. |
format | Text |
id | pubmed-3006865 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30068652010-12-30 (5,15-Dianthracen-9-yl-10,20-dihexylporphyrinato)nickel(II): a planar nickel(II) porphyrin Senge, Mathias O. Davis, Mia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(60)H(52)N(4))], is an example of a meso tetrasubstituted nickel(II) porphyrin with both meso aryl and alkyl residues. The molecule exhibits a planar macrocycle with an average deviation of the 24 macrocycle atoms from their least-squares plane (Δ24) of 0.01 Å and an average Ni—N bond length of 1.960 (2) Å. The Ni(II) atom lies on a center of inversion. The structure presents a rare example for a planar nickel(II) porphyrin, as meso-substituted nickel(II) porphyrins with either only meso-aryl or with meso-alkyl residues typically exhibit a ruffled conformation. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006865/ /pubmed/21587714 http://dx.doi.org/10.1107/S1600536810021434 Text en © Senge and Davis 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Senge, Mathias O. Davis, Mia (5,15-Dianthracen-9-yl-10,20-dihexylporphyrinato)nickel(II): a planar nickel(II) porphyrin |
title | (5,15-Dianthracen-9-yl-10,20-dihexylporphyrinato)nickel(II): a planar nickel(II) porphyrin |
title_full | (5,15-Dianthracen-9-yl-10,20-dihexylporphyrinato)nickel(II): a planar nickel(II) porphyrin |
title_fullStr | (5,15-Dianthracen-9-yl-10,20-dihexylporphyrinato)nickel(II): a planar nickel(II) porphyrin |
title_full_unstemmed | (5,15-Dianthracen-9-yl-10,20-dihexylporphyrinato)nickel(II): a planar nickel(II) porphyrin |
title_short | (5,15-Dianthracen-9-yl-10,20-dihexylporphyrinato)nickel(II): a planar nickel(II) porphyrin |
title_sort | (5,15-dianthracen-9-yl-10,20-dihexylporphyrinato)nickel(ii): a planar nickel(ii) porphyrin |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006865/ https://www.ncbi.nlm.nih.gov/pubmed/21587714 http://dx.doi.org/10.1107/S1600536810021434 |
work_keys_str_mv | AT sengemathiaso 515dianthracen9yl1020dihexylporphyrinatonickeliiaplanarnickeliiporphyrin AT davismia 515dianthracen9yl1020dihexylporphyrinatonickeliiaplanarnickeliiporphyrin |