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(5,15-Dianthracen-9-yl-10,20-dihexyl­porphyrinato)nickel(II): a planar nickel(II) porphyrin

The title compound, [Ni(C(60)H(52)N(4))], is an example of a meso tetra­substituted nickel(II) porphyrin with both meso aryl and alkyl residues. The mol­ecule exhibits a planar macrocycle with an average deviation of the 24 macrocycle atoms from their least-squares plane (Δ24) of 0.01 Å and an avera...

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Detalles Bibliográficos
Autores principales: Senge, Mathias O., Davis, Mia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006865/
https://www.ncbi.nlm.nih.gov/pubmed/21587714
http://dx.doi.org/10.1107/S1600536810021434
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author Senge, Mathias O.
Davis, Mia
author_facet Senge, Mathias O.
Davis, Mia
author_sort Senge, Mathias O.
collection PubMed
description The title compound, [Ni(C(60)H(52)N(4))], is an example of a meso tetra­substituted nickel(II) porphyrin with both meso aryl and alkyl residues. The mol­ecule exhibits a planar macrocycle with an average deviation of the 24 macrocycle atoms from their least-squares plane (Δ24) of 0.01 Å and an average Ni—N bond length of 1.960 (2) Å. The Ni(II) atom lies on a center of inversion. The structure presents a rare example for a planar nickel(II) porphyrin, as meso-substituted nickel(II) porphyrins with either only meso-aryl or with meso-alkyl residues typically exhibit a ruffled conformation.
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spelling pubmed-30068652010-12-30 (5,15-Dianthracen-9-yl-10,20-dihexyl­porphyrinato)nickel(II): a planar nickel(II) porphyrin Senge, Mathias O. Davis, Mia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(60)H(52)N(4))], is an example of a meso tetra­substituted nickel(II) porphyrin with both meso aryl and alkyl residues. The mol­ecule exhibits a planar macrocycle with an average deviation of the 24 macrocycle atoms from their least-squares plane (Δ24) of 0.01 Å and an average Ni—N bond length of 1.960 (2) Å. The Ni(II) atom lies on a center of inversion. The structure presents a rare example for a planar nickel(II) porphyrin, as meso-substituted nickel(II) porphyrins with either only meso-aryl or with meso-alkyl residues typically exhibit a ruffled conformation. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006865/ /pubmed/21587714 http://dx.doi.org/10.1107/S1600536810021434 Text en © Senge and Davis 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Senge, Mathias O.
Davis, Mia
(5,15-Dianthracen-9-yl-10,20-dihexyl­porphyrinato)nickel(II): a planar nickel(II) porphyrin
title (5,15-Dianthracen-9-yl-10,20-dihexyl­porphyrinato)nickel(II): a planar nickel(II) porphyrin
title_full (5,15-Dianthracen-9-yl-10,20-dihexyl­porphyrinato)nickel(II): a planar nickel(II) porphyrin
title_fullStr (5,15-Dianthracen-9-yl-10,20-dihexyl­porphyrinato)nickel(II): a planar nickel(II) porphyrin
title_full_unstemmed (5,15-Dianthracen-9-yl-10,20-dihexyl­porphyrinato)nickel(II): a planar nickel(II) porphyrin
title_short (5,15-Dianthracen-9-yl-10,20-dihexyl­porphyrinato)nickel(II): a planar nickel(II) porphyrin
title_sort (5,15-dianthracen-9-yl-10,20-dihexyl­porphyrinato)nickel(ii): a planar nickel(ii) porphyrin
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006865/
https://www.ncbi.nlm.nih.gov/pubmed/21587714
http://dx.doi.org/10.1107/S1600536810021434
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