Sodium samarium tetra­kis­(poly­phosphate), NaSm(PO(3))(4)

NaSm(PO(3))(4) has been prepared by solid state reactions. It belongs to type II of the structural family of M (I) Ln (III)(PO(3))(4) compounds (M (I) = alkali metal and Ln (III) = rare earth metal) and is composed of (∞)(PO(3))(n)](n−) polyphosphate chains with a repeating unit of four PO(4) tetra­...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhao, Dan, Zhang, Lina, Li, Feifei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006867/
https://www.ncbi.nlm.nih.gov/pubmed/21587668
http://dx.doi.org/10.1107/S1600536810022543
_version_ 1782194241476231168
author Zhao, Dan
Zhang, Lina
Li, Feifei
author_facet Zhao, Dan
Zhang, Lina
Li, Feifei
author_sort Zhao, Dan
collection PubMed
description NaSm(PO(3))(4) has been prepared by solid state reactions. It belongs to type II of the structural family of M (I) Ln (III)(PO(3))(4) compounds (M (I) = alkali metal and Ln (III) = rare earth metal) and is composed of (∞)(PO(3))(n)](n−) polyphosphate chains with a repeating unit of four PO(4) tetra­hedra. The chains extend parallel to [100] and share O atoms with irregular SmO(8) polyhedra, forming a three-dimensional framework which delimits tunnels occupied by Na(+) cations in a distorted octa­hedral environment.
format Text
id pubmed-3006867
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30068672010-12-30 Sodium samarium tetra­kis­(poly­phosphate), NaSm(PO(3))(4) Zhao, Dan Zhang, Lina Li, Feifei Acta Crystallogr Sect E Struct Rep Online Inorganic Papers NaSm(PO(3))(4) has been prepared by solid state reactions. It belongs to type II of the structural family of M (I) Ln (III)(PO(3))(4) compounds (M (I) = alkali metal and Ln (III) = rare earth metal) and is composed of (∞)(PO(3))(n)](n−) polyphosphate chains with a repeating unit of four PO(4) tetra­hedra. The chains extend parallel to [100] and share O atoms with irregular SmO(8) polyhedra, forming a three-dimensional framework which delimits tunnels occupied by Na(+) cations in a distorted octa­hedral environment. International Union of Crystallography 2010-06-23 /pmc/articles/PMC3006867/ /pubmed/21587668 http://dx.doi.org/10.1107/S1600536810022543 Text en © Zhao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Zhao, Dan
Zhang, Lina
Li, Feifei
Sodium samarium tetra­kis­(poly­phosphate), NaSm(PO(3))(4)
title Sodium samarium tetra­kis­(poly­phosphate), NaSm(PO(3))(4)
title_full Sodium samarium tetra­kis­(poly­phosphate), NaSm(PO(3))(4)
title_fullStr Sodium samarium tetra­kis­(poly­phosphate), NaSm(PO(3))(4)
title_full_unstemmed Sodium samarium tetra­kis­(poly­phosphate), NaSm(PO(3))(4)
title_short Sodium samarium tetra­kis­(poly­phosphate), NaSm(PO(3))(4)
title_sort sodium samarium tetra­kis­(poly­phosphate), nasm(po(3))(4)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006867/
https://www.ncbi.nlm.nih.gov/pubmed/21587668
http://dx.doi.org/10.1107/S1600536810022543
work_keys_str_mv AT zhaodan sodiumsamariumtetrakispolyphosphatenasmpo34
AT zhanglina sodiumsamariumtetrakispolyphosphatenasmpo34
AT lifeifei sodiumsamariumtetrakispolyphosphatenasmpo34

Ejemplares similares