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3-Methyl-N-(2-methylphenyl)benzamide
The molecular structure of the title compound, C(15)H(15)NO, involves an intramolecular C—H⋯O hydrogen bond. The central amide group –NH—C(=O)– is twisted by 37.95 (12)° out of the meta-substituted benzoyl ring and by 37.88 (12)° out of the ortho-substituted aniline ring. The two benzene rings are...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006868/ https://www.ncbi.nlm.nih.gov/pubmed/21588047 http://dx.doi.org/10.1107/S1600536810024578 |
| Sumario: | The molecular structure of the title compound, C(15)H(15)NO, involves an intramolecular C—H⋯O hydrogen bond. The central amide group –NH—C(=O)– is twisted by 37.95 (12)° out of the meta-substituted benzoyl ring and by 37.88 (12)° out of the ortho-substituted aniline ring. The two benzene rings are inclined to one another at only 4.2 (1)° having an interplanar spacing of ca 0.90 Å. The crystal structure is stabilized by intermolecular N—H⋯O hydrogen bonds, which link the molecules into chains running along the b axis. A weak intermolecular C—H⋯π interaction is also present. |
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