3-Methyl-N-(2-methyl­phen­yl)benzamide

The mol­ecular structure of the title compound, C(15)H(15)NO, involves an intra­molecular C—H⋯O hydrogen bond. The central amide group –NH—C(=O)– is twisted by 37.95 (12)° out of the meta-substituted benzoyl ring and by 37.88 (12)° out of the ortho-substituted aniline ring. The two benzene rings are...

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Autores principales: Gowda, B. Thimme, Tokarčík, Miroslav, Rodrigues, Vinola Z., Kožíšek, Jozef, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006868/
https://www.ncbi.nlm.nih.gov/pubmed/21588047
http://dx.doi.org/10.1107/S1600536810024578
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author Gowda, B. Thimme
Tokarčík, Miroslav
Rodrigues, Vinola Z.
Kožíšek, Jozef
Fuess, Hartmut
author_facet Gowda, B. Thimme
Tokarčík, Miroslav
Rodrigues, Vinola Z.
Kožíšek, Jozef
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The mol­ecular structure of the title compound, C(15)H(15)NO, involves an intra­molecular C—H⋯O hydrogen bond. The central amide group –NH—C(=O)– is twisted by 37.95 (12)° out of the meta-substituted benzoyl ring and by 37.88 (12)° out of the ortho-substituted aniline ring. The two benzene rings are inclined to one another at only 4.2 (1)° having an inter­planar spacing of ca 0.90 Å. The crystal structure is stabilized by inter­molecular N—H⋯O hydrogen bonds, which link the mol­ecules into chains running along the b axis. A weak inter­molecular C—H⋯π inter­action is also present.
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spelling pubmed-30068682010-12-30 3-Methyl-N-(2-methyl­phen­yl)benzamide Gowda, B. Thimme Tokarčík, Miroslav Rodrigues, Vinola Z. Kožíšek, Jozef Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(15)H(15)NO, involves an intra­molecular C—H⋯O hydrogen bond. The central amide group –NH—C(=O)– is twisted by 37.95 (12)° out of the meta-substituted benzoyl ring and by 37.88 (12)° out of the ortho-substituted aniline ring. The two benzene rings are inclined to one another at only 4.2 (1)° having an inter­planar spacing of ca 0.90 Å. The crystal structure is stabilized by inter­molecular N—H⋯O hydrogen bonds, which link the mol­ecules into chains running along the b axis. A weak inter­molecular C—H⋯π inter­action is also present. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006868/ /pubmed/21588047 http://dx.doi.org/10.1107/S1600536810024578 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Tokarčík, Miroslav
Rodrigues, Vinola Z.
Kožíšek, Jozef
Fuess, Hartmut
3-Methyl-N-(2-methyl­phen­yl)benzamide
title 3-Methyl-N-(2-methyl­phen­yl)benzamide
title_full 3-Methyl-N-(2-methyl­phen­yl)benzamide
title_fullStr 3-Methyl-N-(2-methyl­phen­yl)benzamide
title_full_unstemmed 3-Methyl-N-(2-methyl­phen­yl)benzamide
title_short 3-Methyl-N-(2-methyl­phen­yl)benzamide
title_sort 3-methyl-n-(2-methyl­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006868/
https://www.ncbi.nlm.nih.gov/pubmed/21588047
http://dx.doi.org/10.1107/S1600536810024578
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AT fuesshartmut 3methyln2methylphenylbenzamide

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