Ethyl 3,4-dimethyl-5-[(E)-(phenyl­imino)­meth­yl]-1H-pyrrole-2-carboxyl­ate

In the title compound, C(16)H(18)N(2)O(2), the mol­ecule adopts an E conformation about the C=N double bond. The dihedral angle between the pyrrole and phenyl rings is 41.55 (8)°. In the crystal structure, pairs of inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers....

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Detalles Bibliográficos
Autores principales: Wu, Wei-Na, Yang, Lei, Li, Xiao-Xia, Qin, Bao-Feng, Wang, Qiu-Fen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006869/
https://www.ncbi.nlm.nih.gov/pubmed/21587883
http://dx.doi.org/10.1107/S1600536810022051
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author Wu, Wei-Na
Yang, Lei
Li, Xiao-Xia
Qin, Bao-Feng
Wang, Qiu-Fen
author_facet Wu, Wei-Na
Yang, Lei
Li, Xiao-Xia
Qin, Bao-Feng
Wang, Qiu-Fen
author_sort Wu, Wei-Na
collection PubMed
description In the title compound, C(16)H(18)N(2)O(2), the mol­ecule adopts an E conformation about the C=N double bond. The dihedral angle between the pyrrole and phenyl rings is 41.55 (8)°. In the crystal structure, pairs of inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers. In the dimer, the two pyrrole rings are almost coplanar and the two phenyl rings are parallel to each other.
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spelling pubmed-30068692010-12-30 Ethyl 3,4-dimethyl-5-[(E)-(phenyl­imino)­meth­yl]-1H-pyrrole-2-carboxyl­ate Wu, Wei-Na Yang, Lei Li, Xiao-Xia Qin, Bao-Feng Wang, Qiu-Fen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(18)N(2)O(2), the mol­ecule adopts an E conformation about the C=N double bond. The dihedral angle between the pyrrole and phenyl rings is 41.55 (8)°. In the crystal structure, pairs of inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers. In the dimer, the two pyrrole rings are almost coplanar and the two phenyl rings are parallel to each other. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006869/ /pubmed/21587883 http://dx.doi.org/10.1107/S1600536810022051 Text en © Wu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wu, Wei-Na
Yang, Lei
Li, Xiao-Xia
Qin, Bao-Feng
Wang, Qiu-Fen
Ethyl 3,4-dimethyl-5-[(E)-(phenyl­imino)­meth­yl]-1H-pyrrole-2-carboxyl­ate
title Ethyl 3,4-dimethyl-5-[(E)-(phenyl­imino)­meth­yl]-1H-pyrrole-2-carboxyl­ate
title_full Ethyl 3,4-dimethyl-5-[(E)-(phenyl­imino)­meth­yl]-1H-pyrrole-2-carboxyl­ate
title_fullStr Ethyl 3,4-dimethyl-5-[(E)-(phenyl­imino)­meth­yl]-1H-pyrrole-2-carboxyl­ate
title_full_unstemmed Ethyl 3,4-dimethyl-5-[(E)-(phenyl­imino)­meth­yl]-1H-pyrrole-2-carboxyl­ate
title_short Ethyl 3,4-dimethyl-5-[(E)-(phenyl­imino)­meth­yl]-1H-pyrrole-2-carboxyl­ate
title_sort ethyl 3,4-dimethyl-5-[(e)-(phenyl­imino)­meth­yl]-1h-pyrrole-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006869/
https://www.ncbi.nlm.nih.gov/pubmed/21587883
http://dx.doi.org/10.1107/S1600536810022051
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