(7E)-5-Benzyl-7-(2-chloro­benzyl­idene)-3-(2-chloro­phen­yl)-2-phenyl-3,3a,4,5,6,7-hexa­hydro-2H-pyrazolo­[4,3-c]pyridine

In the title 2H-pyrazolo­[4,3-c]pyridine derivative, C(32)H(27)Cl(2)N(3), the dihydro­pyrazole ring adopts an envelope conformation and the piperidine fused ring a twisted-chair conformation. Two short intra­molecular C—H⋯Cl contacts are observed. The crystal packing is characterized by dimeric C—Cl...

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Detalles Bibliográficos
Autores principales: Karthikeyan, N. S., Mahesh, B. Uma, Sathiyanarayanan, K., Raghavaiah, P., Rathore, R. S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006872/
https://www.ncbi.nlm.nih.gov/pubmed/21587951
http://dx.doi.org/10.1107/S1600536810023317
Descripción
Sumario:In the title 2H-pyrazolo­[4,3-c]pyridine derivative, C(32)H(27)Cl(2)N(3), the dihydro­pyrazole ring adopts an envelope conformation and the piperidine fused ring a twisted-chair conformation. Two short intra­molecular C—H⋯Cl contacts are observed. The crystal packing is characterized by dimeric C—Cl⋯π inter­actions involving the 5-benzyl ring, with Cl⋯centroid and closest atomic Cl⋯π distances of 3.778 (2) and 3.366 (4) Å, respectively.

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