Cargando…
(7E)-5-Benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5,6,7-hexahydro-2H-pyrazolo[4,3-c]pyridine
In the title 2H-pyrazolo[4,3-c]pyridine derivative, C(32)H(27)Cl(2)N(3), the dihydropyrazole ring adopts an envelope conformation and the piperidine fused ring a twisted-chair conformation. Two short intramolecular C—H⋯Cl contacts are observed. The crystal packing is characterized by dimeric C—Cl...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006872/ https://www.ncbi.nlm.nih.gov/pubmed/21587951 http://dx.doi.org/10.1107/S1600536810023317 |
| _version_ | 1782194242648539136 |
|---|---|
| author | Karthikeyan, N. S. Mahesh, B. Uma Sathiyanarayanan, K. Raghavaiah, P. Rathore, R. S. |
| author_facet | Karthikeyan, N. S. Mahesh, B. Uma Sathiyanarayanan, K. Raghavaiah, P. Rathore, R. S. |
| author_sort | Karthikeyan, N. S. |
| collection | PubMed |
| description | In the title 2H-pyrazolo[4,3-c]pyridine derivative, C(32)H(27)Cl(2)N(3), the dihydropyrazole ring adopts an envelope conformation and the piperidine fused ring a twisted-chair conformation. Two short intramolecular C—H⋯Cl contacts are observed. The crystal packing is characterized by dimeric C—Cl⋯π interactions involving the 5-benzyl ring, with Cl⋯centroid and closest atomic Cl⋯π distances of 3.778 (2) and 3.366 (4) Å, respectively. |
| format | Text |
| id | pubmed-3006872 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30068722010-12-30 (7E)-5-Benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5,6,7-hexahydro-2H-pyrazolo[4,3-c]pyridine Karthikeyan, N. S. Mahesh, B. Uma Sathiyanarayanan, K. Raghavaiah, P. Rathore, R. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title 2H-pyrazolo[4,3-c]pyridine derivative, C(32)H(27)Cl(2)N(3), the dihydropyrazole ring adopts an envelope conformation and the piperidine fused ring a twisted-chair conformation. Two short intramolecular C—H⋯Cl contacts are observed. The crystal packing is characterized by dimeric C—Cl⋯π interactions involving the 5-benzyl ring, with Cl⋯centroid and closest atomic Cl⋯π distances of 3.778 (2) and 3.366 (4) Å, respectively. International Union of Crystallography 2010-06-23 /pmc/articles/PMC3006872/ /pubmed/21587951 http://dx.doi.org/10.1107/S1600536810023317 Text en © Karthikeyan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Karthikeyan, N. S. Mahesh, B. Uma Sathiyanarayanan, K. Raghavaiah, P. Rathore, R. S. (7E)-5-Benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5,6,7-hexahydro-2H-pyrazolo[4,3-c]pyridine |
| title | (7E)-5-Benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5,6,7-hexahydro-2H-pyrazolo[4,3-c]pyridine |
| title_full | (7E)-5-Benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5,6,7-hexahydro-2H-pyrazolo[4,3-c]pyridine |
| title_fullStr | (7E)-5-Benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5,6,7-hexahydro-2H-pyrazolo[4,3-c]pyridine |
| title_full_unstemmed | (7E)-5-Benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5,6,7-hexahydro-2H-pyrazolo[4,3-c]pyridine |
| title_short | (7E)-5-Benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5,6,7-hexahydro-2H-pyrazolo[4,3-c]pyridine |
| title_sort | (7e)-5-benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5,6,7-hexahydro-2h-pyrazolo[4,3-c]pyridine |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006872/ https://www.ncbi.nlm.nih.gov/pubmed/21587951 http://dx.doi.org/10.1107/S1600536810023317 |
| work_keys_str_mv | AT karthikeyanns 7e5benzyl72chlorobenzylidene32chlorophenyl2phenyl33a4567hexahydro2hpyrazolo43cpyridine AT maheshbuma 7e5benzyl72chlorobenzylidene32chlorophenyl2phenyl33a4567hexahydro2hpyrazolo43cpyridine AT sathiyanarayanank 7e5benzyl72chlorobenzylidene32chlorophenyl2phenyl33a4567hexahydro2hpyrazolo43cpyridine AT raghavaiahp 7e5benzyl72chlorobenzylidene32chlorophenyl2phenyl33a4567hexahydro2hpyrazolo43cpyridine AT rathorers 7e5benzyl72chlorobenzylidene32chlorophenyl2phenyl33a4567hexahydro2hpyrazolo43cpyridine |