(1R,3S,4R,4aS,7R,7aS,10R,12aR)-3-Azido-4,7,10-trimethyl-1,10-epidioxy­per­hydropyrano[4,3-j][1,2]benzodiox­epine

In the title compound, C(15)H(23)N(3)O(4), the six-membered pyran, cyclo­hexane and trioxane rings adopt chair, chair and boat conformations, respectively, while the seven-membered rings adopt distorted boat and very distorted chair conformations. In the crystal, adjacent mol­ecules are connected by...

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Detalles Bibliográficos
Autores principales: Xie, Lijun, Zhai, Xin, Zuo, Jian, Zhao, Yanfang, Gong, Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006879/
https://www.ncbi.nlm.nih.gov/pubmed/21588040
http://dx.doi.org/10.1107/S1600536810024566
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author Xie, Lijun
Zhai, Xin
Zuo, Jian
Zhao, Yanfang
Gong, Ping
author_facet Xie, Lijun
Zhai, Xin
Zuo, Jian
Zhao, Yanfang
Gong, Ping
author_sort Xie, Lijun
collection PubMed
description In the title compound, C(15)H(23)N(3)O(4), the six-membered pyran, cyclo­hexane and trioxane rings adopt chair, chair and boat conformations, respectively, while the seven-membered rings adopt distorted boat and very distorted chair conformations. In the crystal, adjacent mol­ecules are connected by weak C—H⋯N and C—H⋯O inter­actions.
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spelling pubmed-30068792010-12-30 (1R,3S,4R,4aS,7R,7aS,10R,12aR)-3-Azido-4,7,10-trimethyl-1,10-epidioxy­per­hydropyrano[4,3-j][1,2]benzodiox­epine Xie, Lijun Zhai, Xin Zuo, Jian Zhao, Yanfang Gong, Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(23)N(3)O(4), the six-membered pyran, cyclo­hexane and trioxane rings adopt chair, chair and boat conformations, respectively, while the seven-membered rings adopt distorted boat and very distorted chair conformations. In the crystal, adjacent mol­ecules are connected by weak C—H⋯N and C—H⋯O inter­actions. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006879/ /pubmed/21588040 http://dx.doi.org/10.1107/S1600536810024566 Text en © Xie et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xie, Lijun
Zhai, Xin
Zuo, Jian
Zhao, Yanfang
Gong, Ping
(1R,3S,4R,4aS,7R,7aS,10R,12aR)-3-Azido-4,7,10-trimethyl-1,10-epidioxy­per­hydropyrano[4,3-j][1,2]benzodiox­epine
title (1R,3S,4R,4aS,7R,7aS,10R,12aR)-3-Azido-4,7,10-trimethyl-1,10-epidioxy­per­hydropyrano[4,3-j][1,2]benzodiox­epine
title_full (1R,3S,4R,4aS,7R,7aS,10R,12aR)-3-Azido-4,7,10-trimethyl-1,10-epidioxy­per­hydropyrano[4,3-j][1,2]benzodiox­epine
title_fullStr (1R,3S,4R,4aS,7R,7aS,10R,12aR)-3-Azido-4,7,10-trimethyl-1,10-epidioxy­per­hydropyrano[4,3-j][1,2]benzodiox­epine
title_full_unstemmed (1R,3S,4R,4aS,7R,7aS,10R,12aR)-3-Azido-4,7,10-trimethyl-1,10-epidioxy­per­hydropyrano[4,3-j][1,2]benzodiox­epine
title_short (1R,3S,4R,4aS,7R,7aS,10R,12aR)-3-Azido-4,7,10-trimethyl-1,10-epidioxy­per­hydropyrano[4,3-j][1,2]benzodiox­epine
title_sort (1r,3s,4r,4as,7r,7as,10r,12ar)-3-azido-4,7,10-trimethyl-1,10-epidioxy­per­hydropyrano[4,3-j][1,2]benzodiox­epine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006879/
https://www.ncbi.nlm.nih.gov/pubmed/21588040
http://dx.doi.org/10.1107/S1600536810024566
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