Dimethyl 2,2′-[ethane-1,2-diylbis(sulfanedi­yl)]dibenzoate

The title compound, C(18)H(18)O(4)S(2), was synthesized by the reaction of 1,2-dibromo­ethane with methyl thio­salicylate. The complete molecule is generated by crystallographic twofold symmetry: two methyl benzoate units are linked by an –S–(CH(2))(2)–S– bridging chain with a gauche S—CH(2)—CH(2)—S...

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Detalles Bibliográficos
Autores principales: Hu, Xiaoming, Yu, Jianghua, Yuan, Limin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006883/
https://www.ncbi.nlm.nih.gov/pubmed/21587900
http://dx.doi.org/10.1107/S1600536810022403
Descripción
Sumario:The title compound, C(18)H(18)O(4)S(2), was synthesized by the reaction of 1,2-dibromo­ethane with methyl thio­salicylate. The complete molecule is generated by crystallographic twofold symmetry: two methyl benzoate units are linked by an –S–(CH(2))(2)–S– bridging chain with a gauche S—CH(2)—CH(2)—S torsion angle [72.88 (16)°]. The two aromatic rings form a dihedral angle of 79.99 (6)°. In the crystal, adjacent mol­ecules are linked into a three-dimensional network by non-classical C—H⋯O hydrogen bonds.

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