Dimethyl 2,2′-[ethane-1,2-diylbis(sulfanedi­yl)]dibenzoate

The title compound, C(18)H(18)O(4)S(2), was synthesized by the reaction of 1,2-dibromo­ethane with methyl thio­salicylate. The complete molecule is generated by crystallographic twofold symmetry: two methyl benzoate units are linked by an –S–(CH(2))(2)–S– bridging chain with a gauche S—CH(2)—CH(2)—S...

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Detalles Bibliográficos
Autores principales: Hu, Xiaoming, Yu, Jianghua, Yuan, Limin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006883/
https://www.ncbi.nlm.nih.gov/pubmed/21587900
http://dx.doi.org/10.1107/S1600536810022403
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author Hu, Xiaoming
Yu, Jianghua
Yuan, Limin
author_facet Hu, Xiaoming
Yu, Jianghua
Yuan, Limin
author_sort Hu, Xiaoming
collection PubMed
description The title compound, C(18)H(18)O(4)S(2), was synthesized by the reaction of 1,2-dibromo­ethane with methyl thio­salicylate. The complete molecule is generated by crystallographic twofold symmetry: two methyl benzoate units are linked by an –S–(CH(2))(2)–S– bridging chain with a gauche S—CH(2)—CH(2)—S torsion angle [72.88 (16)°]. The two aromatic rings form a dihedral angle of 79.99 (6)°. In the crystal, adjacent mol­ecules are linked into a three-dimensional network by non-classical C—H⋯O hydrogen bonds.
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spelling pubmed-30068832010-12-30 Dimethyl 2,2′-[ethane-1,2-diylbis(sulfanedi­yl)]dibenzoate Hu, Xiaoming Yu, Jianghua Yuan, Limin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(18)O(4)S(2), was synthesized by the reaction of 1,2-dibromo­ethane with methyl thio­salicylate. The complete molecule is generated by crystallographic twofold symmetry: two methyl benzoate units are linked by an –S–(CH(2))(2)–S– bridging chain with a gauche S—CH(2)—CH(2)—S torsion angle [72.88 (16)°]. The two aromatic rings form a dihedral angle of 79.99 (6)°. In the crystal, adjacent mol­ecules are linked into a three-dimensional network by non-classical C—H⋯O hydrogen bonds. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006883/ /pubmed/21587900 http://dx.doi.org/10.1107/S1600536810022403 Text en © Hu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hu, Xiaoming
Yu, Jianghua
Yuan, Limin
Dimethyl 2,2′-[ethane-1,2-diylbis(sulfanedi­yl)]dibenzoate
title Dimethyl 2,2′-[ethane-1,2-diylbis(sulfanedi­yl)]dibenzoate
title_full Dimethyl 2,2′-[ethane-1,2-diylbis(sulfanedi­yl)]dibenzoate
title_fullStr Dimethyl 2,2′-[ethane-1,2-diylbis(sulfanedi­yl)]dibenzoate
title_full_unstemmed Dimethyl 2,2′-[ethane-1,2-diylbis(sulfanedi­yl)]dibenzoate
title_short Dimethyl 2,2′-[ethane-1,2-diylbis(sulfanedi­yl)]dibenzoate
title_sort dimethyl 2,2′-[ethane-1,2-diylbis(sulfanedi­yl)]dibenzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006883/
https://www.ncbi.nlm.nih.gov/pubmed/21587900
http://dx.doi.org/10.1107/S1600536810022403
work_keys_str_mv AT huxiaoming dimethyl22ethane12diylbissulfanediyldibenzoate
AT yujianghua dimethyl22ethane12diylbissulfanediyldibenzoate
AT yuanlimin dimethyl22ethane12diylbissulfanediyldibenzoate

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