Dicylopenta­dien­yl[4-(4-vinyl­benz­yloxy)pyridine-2,6-dicarboxyl­ato]titanium(IV) monohydrate

The title compound, [Ti(C(5)H(5))(2)(C(16)H(11)NO(5))]·H(2)O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxyl­ate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhu, Fanghua, Qin, Yuancheng, Lei, Jiehong, Zhang, Lin, Yin, Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006885/
https://www.ncbi.nlm.nih.gov/pubmed/21587700
http://dx.doi.org/10.1107/S1600536810021148
_version_ 1782194245747081216
author Zhu, Fanghua
Qin, Yuancheng
Lei, Jiehong
Zhang, Lin
Yin, Qiang
author_facet Zhu, Fanghua
Qin, Yuancheng
Lei, Jiehong
Zhang, Lin
Yin, Qiang
author_sort Zhu, Fanghua
collection PubMed
description The title compound, [Ti(C(5)H(5))(2)(C(16)H(11)NO(5))]·H(2)O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxyl­ate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized as a monohydrate and the solvent water mol­ecule forms strong O—H⋯O hydrogen bonds with the carboxyl­ate O atoms of the Ti complex, which play an important role in the connection of adjacent mol­ecules. In addition, weak inter­molecular C—H⋯O hydrogen bonds also contribute to the crystal packing arrangement.
format Text
id pubmed-3006885
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30068852010-12-30 Dicylopenta­dien­yl[4-(4-vinyl­benz­yloxy)pyridine-2,6-dicarboxyl­ato]titanium(IV) monohydrate Zhu, Fanghua Qin, Yuancheng Lei, Jiehong Zhang, Lin Yin, Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ti(C(5)H(5))(2)(C(16)H(11)NO(5))]·H(2)O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxyl­ate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized as a monohydrate and the solvent water mol­ecule forms strong O—H⋯O hydrogen bonds with the carboxyl­ate O atoms of the Ti complex, which play an important role in the connection of adjacent mol­ecules. In addition, weak inter­molecular C—H⋯O hydrogen bonds also contribute to the crystal packing arrangement. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006885/ /pubmed/21587700 http://dx.doi.org/10.1107/S1600536810021148 Text en © Zhu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Fanghua
Qin, Yuancheng
Lei, Jiehong
Zhang, Lin
Yin, Qiang
Dicylopenta­dien­yl[4-(4-vinyl­benz­yloxy)pyridine-2,6-dicarboxyl­ato]titanium(IV) monohydrate
title Dicylopenta­dien­yl[4-(4-vinyl­benz­yloxy)pyridine-2,6-dicarboxyl­ato]titanium(IV) monohydrate
title_full Dicylopenta­dien­yl[4-(4-vinyl­benz­yloxy)pyridine-2,6-dicarboxyl­ato]titanium(IV) monohydrate
title_fullStr Dicylopenta­dien­yl[4-(4-vinyl­benz­yloxy)pyridine-2,6-dicarboxyl­ato]titanium(IV) monohydrate
title_full_unstemmed Dicylopenta­dien­yl[4-(4-vinyl­benz­yloxy)pyridine-2,6-dicarboxyl­ato]titanium(IV) monohydrate
title_short Dicylopenta­dien­yl[4-(4-vinyl­benz­yloxy)pyridine-2,6-dicarboxyl­ato]titanium(IV) monohydrate
title_sort dicylopenta­dien­yl[4-(4-vinyl­benz­yloxy)pyridine-2,6-dicarboxyl­ato]titanium(iv) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006885/
https://www.ncbi.nlm.nih.gov/pubmed/21587700
http://dx.doi.org/10.1107/S1600536810021148
work_keys_str_mv AT zhufanghua dicylopentadienyl44vinylbenzyloxypyridine26dicarboxylatotitaniumivmonohydrate
AT qinyuancheng dicylopentadienyl44vinylbenzyloxypyridine26dicarboxylatotitaniumivmonohydrate
AT leijiehong dicylopentadienyl44vinylbenzyloxypyridine26dicarboxylatotitaniumivmonohydrate
AT zhanglin dicylopentadienyl44vinylbenzyloxypyridine26dicarboxylatotitaniumivmonohydrate
AT yinqiang dicylopentadienyl44vinylbenzyloxypyridine26dicarboxylatotitaniumivmonohydrate

Ejemplares similares