Poly[(μ(3)-4-amino­benzene­sulfonato-κ(3) N:O:O)(triphenyl­phosphine-κP)silver(I)]

In the title 1:1 silver 4-amino­benzene­sulfonate adduct with triphenyl­phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon­ate –SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerabl...

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Detalles Bibliográficos
Autores principales: Sadeghi, Omid, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006886/
https://www.ncbi.nlm.nih.gov/pubmed/21587763
http://dx.doi.org/10.1107/S1600536810024207
Descripción
Sumario:In the title 1:1 silver 4-amino­benzene­sulfonate adduct with triphenyl­phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon­ate –SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra­hedral coordination. In the crystal, adjacent binuclear mol­ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis.

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