Poly[(μ(3)-4-amino­benzene­sulfonato-κ(3) N:O:O)(triphenyl­phosphine-κP)silver(I)]

In the title 1:1 silver 4-amino­benzene­sulfonate adduct with triphenyl­phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon­ate –SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerabl...

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Detalles Bibliográficos
Autores principales: Sadeghi, Omid, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006886/
https://www.ncbi.nlm.nih.gov/pubmed/21587763
http://dx.doi.org/10.1107/S1600536810024207
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author Sadeghi, Omid
Amini, Mostafa M.
Ng, Seik Weng
author_facet Sadeghi, Omid
Amini, Mostafa M.
Ng, Seik Weng
author_sort Sadeghi, Omid
collection PubMed
description In the title 1:1 silver 4-amino­benzene­sulfonate adduct with triphenyl­phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon­ate –SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra­hedral coordination. In the crystal, adjacent binuclear mol­ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis.
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spelling pubmed-30068862010-12-30 Poly[(μ(3)-4-amino­benzene­sulfonato-κ(3) N:O:O)(triphenyl­phosphine-κP)silver(I)] Sadeghi, Omid Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title 1:1 silver 4-amino­benzene­sulfonate adduct with triphenyl­phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon­ate –SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra­hedral coordination. In the crystal, adjacent binuclear mol­ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006886/ /pubmed/21587763 http://dx.doi.org/10.1107/S1600536810024207 Text en © Sadeghi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sadeghi, Omid
Amini, Mostafa M.
Ng, Seik Weng
Poly[(μ(3)-4-amino­benzene­sulfonato-κ(3) N:O:O)(triphenyl­phosphine-κP)silver(I)]
title Poly[(μ(3)-4-amino­benzene­sulfonato-κ(3) N:O:O)(triphenyl­phosphine-κP)silver(I)]
title_full Poly[(μ(3)-4-amino­benzene­sulfonato-κ(3) N:O:O)(triphenyl­phosphine-κP)silver(I)]
title_fullStr Poly[(μ(3)-4-amino­benzene­sulfonato-κ(3) N:O:O)(triphenyl­phosphine-κP)silver(I)]
title_full_unstemmed Poly[(μ(3)-4-amino­benzene­sulfonato-κ(3) N:O:O)(triphenyl­phosphine-κP)silver(I)]
title_short Poly[(μ(3)-4-amino­benzene­sulfonato-κ(3) N:O:O)(triphenyl­phosphine-κP)silver(I)]
title_sort poly[(μ(3)-4-amino­benzene­sulfonato-κ(3) n:o:o)(triphenyl­phosphine-κp)silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006886/
https://www.ncbi.nlm.nih.gov/pubmed/21587763
http://dx.doi.org/10.1107/S1600536810024207
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AT aminimostafam polym34aminobenzenesulfonatok3nootriphenylphosphinekpsilveri
AT ngseikweng polym34aminobenzenesulfonatok3nootriphenylphosphinekpsilveri

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