Chlorido[hydridotris(pyrazol-1-yl-κN (2))borato](1H-pyrazole-κN (2))(triphenyl­phosphine-κP)ruthenium(II)

In the title compound, [Ru(C(9)H(10)BN(6))Cl(C(3)H(4)N(2))(C(18)H(15)P)], the Ru(II) atom is coordinated by an N,N′,N′′-tridentate hydrido­trispyrazolylborate (Tp) ligand, a pyrazole (HPz) mol­ecule, a chloride ion and a triphenyl­phosphine ligand, resulting in a distorted RuClPN(4) octa­hedral coor...

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Detalles Bibliográficos
Autores principales: Huang, Chiung-Cheng, Chen, Han-Gung, Lo, Yih Hsing, Hsu, Li-Sheng, Lin, Chia-Her
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006890/
https://www.ncbi.nlm.nih.gov/pubmed/21587719
http://dx.doi.org/10.1107/S1600536810021525
Descripción
Sumario:In the title compound, [Ru(C(9)H(10)BN(6))Cl(C(3)H(4)N(2))(C(18)H(15)P)], the Ru(II) atom is coordinated by an N,N′,N′′-tridentate hydrido­trispyrazolylborate (Tp) ligand, a pyrazole (HPz) mol­ecule, a chloride ion and a triphenyl­phosphine ligand, resulting in a distorted RuClPN(4) octa­hedral coordination for the metal ion: the tridentate N atoms occupy one octa­hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra­molecular N—H⋯Cl hydrogen bond generates an S(5) ring.

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