Chlorido[hydridotris(pyrazol-1-yl-κN (2))borato](1H-pyrazole-κN (2))(triphenyl­phosphine-κP)ruthenium(II)

In the title compound, [Ru(C(9)H(10)BN(6))Cl(C(3)H(4)N(2))(C(18)H(15)P)], the Ru(II) atom is coordinated by an N,N′,N′′-tridentate hydrido­trispyrazolylborate (Tp) ligand, a pyrazole (HPz) mol­ecule, a chloride ion and a triphenyl­phosphine ligand, resulting in a distorted RuClPN(4) octa­hedral coor...

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Autores principales: Huang, Chiung-Cheng, Chen, Han-Gung, Lo, Yih Hsing, Hsu, Li-Sheng, Lin, Chia-Her
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006890/
https://www.ncbi.nlm.nih.gov/pubmed/21587719
http://dx.doi.org/10.1107/S1600536810021525
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author Huang, Chiung-Cheng
Chen, Han-Gung
Lo, Yih Hsing
Hsu, Li-Sheng
Lin, Chia-Her
author_facet Huang, Chiung-Cheng
Chen, Han-Gung
Lo, Yih Hsing
Hsu, Li-Sheng
Lin, Chia-Her
author_sort Huang, Chiung-Cheng
collection PubMed
description In the title compound, [Ru(C(9)H(10)BN(6))Cl(C(3)H(4)N(2))(C(18)H(15)P)], the Ru(II) atom is coordinated by an N,N′,N′′-tridentate hydrido­trispyrazolylborate (Tp) ligand, a pyrazole (HPz) mol­ecule, a chloride ion and a triphenyl­phosphine ligand, resulting in a distorted RuClPN(4) octa­hedral coordination for the metal ion: the tridentate N atoms occupy one octa­hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra­molecular N—H⋯Cl hydrogen bond generates an S(5) ring.
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spelling pubmed-30068902010-12-30 Chlorido[hydridotris(pyrazol-1-yl-κN (2))borato](1H-pyrazole-κN (2))(triphenyl­phosphine-κP)ruthenium(II) Huang, Chiung-Cheng Chen, Han-Gung Lo, Yih Hsing Hsu, Li-Sheng Lin, Chia-Her Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(C(9)H(10)BN(6))Cl(C(3)H(4)N(2))(C(18)H(15)P)], the Ru(II) atom is coordinated by an N,N′,N′′-tridentate hydrido­trispyrazolylborate (Tp) ligand, a pyrazole (HPz) mol­ecule, a chloride ion and a triphenyl­phosphine ligand, resulting in a distorted RuClPN(4) octa­hedral coordination for the metal ion: the tridentate N atoms occupy one octa­hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra­molecular N—H⋯Cl hydrogen bond generates an S(5) ring. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006890/ /pubmed/21587719 http://dx.doi.org/10.1107/S1600536810021525 Text en © Chen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Chiung-Cheng
Chen, Han-Gung
Lo, Yih Hsing
Hsu, Li-Sheng
Lin, Chia-Her
Chlorido[hydridotris(pyrazol-1-yl-κN (2))borato](1H-pyrazole-κN (2))(triphenyl­phosphine-κP)ruthenium(II)
title Chlorido[hydridotris(pyrazol-1-yl-κN (2))borato](1H-pyrazole-κN (2))(triphenyl­phosphine-κP)ruthenium(II)
title_full Chlorido[hydridotris(pyrazol-1-yl-κN (2))borato](1H-pyrazole-κN (2))(triphenyl­phosphine-κP)ruthenium(II)
title_fullStr Chlorido[hydridotris(pyrazol-1-yl-κN (2))borato](1H-pyrazole-κN (2))(triphenyl­phosphine-κP)ruthenium(II)
title_full_unstemmed Chlorido[hydridotris(pyrazol-1-yl-κN (2))borato](1H-pyrazole-κN (2))(triphenyl­phosphine-κP)ruthenium(II)
title_short Chlorido[hydridotris(pyrazol-1-yl-κN (2))borato](1H-pyrazole-κN (2))(triphenyl­phosphine-κP)ruthenium(II)
title_sort chlorido[hydridotris(pyrazol-1-yl-κn (2))borato](1h-pyrazole-κn (2))(triphenyl­phosphine-κp)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006890/
https://www.ncbi.nlm.nih.gov/pubmed/21587719
http://dx.doi.org/10.1107/S1600536810021525
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