N-(4,5-Diaza-9H-fluoren-9-yl­idene)-4-meth­oxy­aniline

In the title compound, C(18)H(13)N(3)O, the diaza­fluorene ring system is almost coplanar (r.m.s. deviation = 0.0640 Å) and subtends an angle of 61.5 (4)° with the plane of the meth­oxy-substituted benzene ring. In the crystal structure, pairs of C—H⋯O hydrogen bonds link mol­ecules into centrosymme...

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Detalles Bibliográficos
Autores principales: Cang, Hui, Bian, Jin-Fa, Wang, Si-Qing, Wang, Jin-Tang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006891/
https://www.ncbi.nlm.nih.gov/pubmed/21588013
http://dx.doi.org/10.1107/S1600536810023275
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author Cang, Hui
Bian, Jin-Fa
Wang, Si-Qing
Wang, Jin-Tang
author_facet Cang, Hui
Bian, Jin-Fa
Wang, Si-Qing
Wang, Jin-Tang
author_sort Cang, Hui
collection PubMed
description In the title compound, C(18)H(13)N(3)O, the diaza­fluorene ring system is almost coplanar (r.m.s. deviation = 0.0640 Å) and subtends an angle of 61.5 (4)° with the plane of the meth­oxy-substituted benzene ring. In the crystal structure, pairs of C—H⋯O hydrogen bonds link mol­ecules into centrosymmetric dimers parallel to the ab plane. Mol­ecules are also stacked in an obverse fashion along the c axis by a variety of π–π inter­actions with centroid–centroid distances in the range 3.557 (2)–3.921 (2) Å.
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spelling pubmed-30068912010-12-30 N-(4,5-Diaza-9H-fluoren-9-yl­idene)-4-meth­oxy­aniline Cang, Hui Bian, Jin-Fa Wang, Si-Qing Wang, Jin-Tang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(13)N(3)O, the diaza­fluorene ring system is almost coplanar (r.m.s. deviation = 0.0640 Å) and subtends an angle of 61.5 (4)° with the plane of the meth­oxy-substituted benzene ring. In the crystal structure, pairs of C—H⋯O hydrogen bonds link mol­ecules into centrosymmetric dimers parallel to the ab plane. Mol­ecules are also stacked in an obverse fashion along the c axis by a variety of π–π inter­actions with centroid–centroid distances in the range 3.557 (2)–3.921 (2) Å. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006891/ /pubmed/21588013 http://dx.doi.org/10.1107/S1600536810023275 Text en © Cang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cang, Hui
Bian, Jin-Fa
Wang, Si-Qing
Wang, Jin-Tang
N-(4,5-Diaza-9H-fluoren-9-yl­idene)-4-meth­oxy­aniline
title N-(4,5-Diaza-9H-fluoren-9-yl­idene)-4-meth­oxy­aniline
title_full N-(4,5-Diaza-9H-fluoren-9-yl­idene)-4-meth­oxy­aniline
title_fullStr N-(4,5-Diaza-9H-fluoren-9-yl­idene)-4-meth­oxy­aniline
title_full_unstemmed N-(4,5-Diaza-9H-fluoren-9-yl­idene)-4-meth­oxy­aniline
title_short N-(4,5-Diaza-9H-fluoren-9-yl­idene)-4-meth­oxy­aniline
title_sort n-(4,5-diaza-9h-fluoren-9-yl­idene)-4-meth­oxy­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006891/
https://www.ncbi.nlm.nih.gov/pubmed/21588013
http://dx.doi.org/10.1107/S1600536810023275
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