Bis(2-amino-3H-benzothia­zolium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cobaltate(II) hexa­hydrate

In the crystal structure of the title salt, (C(7)H(7)N(2)S)(2)[Co(C(8)H(8)O(5))(2)]·6H(2)O, the heterocyclic N atom of the 2-amino­benzothia­zole mol­ecule is protonated. The Co(II) atom is situated on an inversion centre and exhibits a slightly distorted octa­hedral CoO(6) coordination defined by t...

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Detalles Bibliográficos
Autores principales: Wang, Na, Lin, Qiu-Yue, Feng, Jie, Li, Shi-Kun, Zhao, Jun-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006894/
https://www.ncbi.nlm.nih.gov/pubmed/21587697
http://dx.doi.org/10.1107/S1600536810020921
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author Wang, Na
Lin, Qiu-Yue
Feng, Jie
Li, Shi-Kun
Zhao, Jun-Jun
author_facet Wang, Na
Lin, Qiu-Yue
Feng, Jie
Li, Shi-Kun
Zhao, Jun-Jun
author_sort Wang, Na
collection PubMed
description In the crystal structure of the title salt, (C(7)H(7)N(2)S)(2)[Co(C(8)H(8)O(5))(2)]·6H(2)O, the heterocyclic N atom of the 2-amino­benzothia­zole mol­ecule is protonated. The Co(II) atom is situated on an inversion centre and exhibits a slightly distorted octa­hedral CoO(6) coordination defined by the bridging O atoms of the bicyclo­heptane unit and four carboxyl­ate O atoms of two symmetry-related and fully deprotonated ligands. The crystal packing is stabilized by N—H⋯O hydrogen bonds between the cations and anions and by O—H⋯O hydrogen bonds including the crystal water mol­ecules.
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spelling pubmed-30068942010-12-30 Bis(2-amino-3H-benzothia­zolium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cobaltate(II) hexa­hydrate Wang, Na Lin, Qiu-Yue Feng, Jie Li, Shi-Kun Zhao, Jun-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title salt, (C(7)H(7)N(2)S)(2)[Co(C(8)H(8)O(5))(2)]·6H(2)O, the heterocyclic N atom of the 2-amino­benzothia­zole mol­ecule is protonated. The Co(II) atom is situated on an inversion centre and exhibits a slightly distorted octa­hedral CoO(6) coordination defined by the bridging O atoms of the bicyclo­heptane unit and four carboxyl­ate O atoms of two symmetry-related and fully deprotonated ligands. The crystal packing is stabilized by N—H⋯O hydrogen bonds between the cations and anions and by O—H⋯O hydrogen bonds including the crystal water mol­ecules. International Union of Crystallography 2010-06-09 /pmc/articles/PMC3006894/ /pubmed/21587697 http://dx.doi.org/10.1107/S1600536810020921 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Na
Lin, Qiu-Yue
Feng, Jie
Li, Shi-Kun
Zhao, Jun-Jun
Bis(2-amino-3H-benzothia­zolium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cobaltate(II) hexa­hydrate
title Bis(2-amino-3H-benzothia­zolium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cobaltate(II) hexa­hydrate
title_full Bis(2-amino-3H-benzothia­zolium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cobaltate(II) hexa­hydrate
title_fullStr Bis(2-amino-3H-benzothia­zolium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cobaltate(II) hexa­hydrate
title_full_unstemmed Bis(2-amino-3H-benzothia­zolium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cobaltate(II) hexa­hydrate
title_short Bis(2-amino-3H-benzothia­zolium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cobaltate(II) hexa­hydrate
title_sort bis(2-amino-3h-benzothia­zolium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cobaltate(ii) hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006894/
https://www.ncbi.nlm.nih.gov/pubmed/21587697
http://dx.doi.org/10.1107/S1600536810020921
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