Poly[3,3′-diethyl-1,1′-(ethane-1,2-di­yl)diimidazolium [tetra-μ-bromido-­diargentate(I)]]

The asymmetric unit of the title salt, {(C(12)H(20)N(4))[Ag(2)Br(4)]}(n), contains one-half of a substituted imidazolium cation, one Ag(+) and two Br(−) ions. The cation is completed by crystallographic inversion symmetry. The crystal structure is made up from polymeric sheets of {[AgBr(2)](−)}(n) a...

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Detalles Bibliográficos
Autores principales: Wang, Zhiguo, Liu, Siman, Zhang, Na
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006904/
https://www.ncbi.nlm.nih.gov/pubmed/21587756
http://dx.doi.org/10.1107/S160053681002146X
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author Wang, Zhiguo
Liu, Siman
Zhang, Na
author_facet Wang, Zhiguo
Liu, Siman
Zhang, Na
author_sort Wang, Zhiguo
collection PubMed
description The asymmetric unit of the title salt, {(C(12)H(20)N(4))[Ag(2)Br(4)]}(n), contains one-half of a substituted imidazolium cation, one Ag(+) and two Br(−) ions. The cation is completed by crystallographic inversion symmetry. The crystal structure is made up from polymeric sheets of {[AgBr(2)](−)}(n) anions extending parallel to (100). The basic building unit of the anion is a slightly distorted AgBr(4) tetra­hedron. A four- and 12-membered ring system is formed by corner sharing of the AgBr(4) tetra­hedra. The imidazolium cations are located between the anionic sheets and partly protrude into the voids defined by the 12-membered rings.
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spelling pubmed-30069042010-12-30 Poly[3,3′-diethyl-1,1′-(ethane-1,2-di­yl)diimidazolium [tetra-μ-bromido-­diargentate(I)]] Wang, Zhiguo Liu, Siman Zhang, Na Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title salt, {(C(12)H(20)N(4))[Ag(2)Br(4)]}(n), contains one-half of a substituted imidazolium cation, one Ag(+) and two Br(−) ions. The cation is completed by crystallographic inversion symmetry. The crystal structure is made up from polymeric sheets of {[AgBr(2)](−)}(n) anions extending parallel to (100). The basic building unit of the anion is a slightly distorted AgBr(4) tetra­hedron. A four- and 12-membered ring system is formed by corner sharing of the AgBr(4) tetra­hedra. The imidazolium cations are located between the anionic sheets and partly protrude into the voids defined by the 12-membered rings. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006904/ /pubmed/21587756 http://dx.doi.org/10.1107/S160053681002146X Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zhiguo
Liu, Siman
Zhang, Na
Poly[3,3′-diethyl-1,1′-(ethane-1,2-di­yl)diimidazolium [tetra-μ-bromido-­diargentate(I)]]
title Poly[3,3′-diethyl-1,1′-(ethane-1,2-di­yl)diimidazolium [tetra-μ-bromido-­diargentate(I)]]
title_full Poly[3,3′-diethyl-1,1′-(ethane-1,2-di­yl)diimidazolium [tetra-μ-bromido-­diargentate(I)]]
title_fullStr Poly[3,3′-diethyl-1,1′-(ethane-1,2-di­yl)diimidazolium [tetra-μ-bromido-­diargentate(I)]]
title_full_unstemmed Poly[3,3′-diethyl-1,1′-(ethane-1,2-di­yl)diimidazolium [tetra-μ-bromido-­diargentate(I)]]
title_short Poly[3,3′-diethyl-1,1′-(ethane-1,2-di­yl)diimidazolium [tetra-μ-bromido-­diargentate(I)]]
title_sort poly[3,3′-diethyl-1,1′-(ethane-1,2-di­yl)diimidazolium [tetra-μ-bromido-­diargentate(i)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006904/
https://www.ncbi.nlm.nih.gov/pubmed/21587756
http://dx.doi.org/10.1107/S160053681002146X
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AT zhangna poly33diethyl11ethane12diyldiimidazoliumtetrambromidodiargentatei

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