trans-Dichlorido(2,2-dimethyl­propane-1,3-diamine)­bis­(triphenyl­phosphane)ruthenium(II)

In the title compound, [RuCl(2)(C(5)H(14)N(2))(C(18)H(15)P)(2)], the Ru(II) atom is six-coordinated, forming a slightly distorted octa­hedral geometry, with two chloride ions in an axial arrangement, and two P atoms of two triphenyl­phosphane and two chelating N atoms of the bidentate 2,2-dimethyl­p...

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Detalles Bibliográficos
Autores principales: Khanfar, Monther A., Warad, Ismail, AlDamen, Murad A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006909/
https://www.ncbi.nlm.nih.gov/pubmed/21587674
http://dx.doi.org/10.1107/S1600536810019276
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author Khanfar, Monther A.
Warad, Ismail
AlDamen, Murad A.
author_facet Khanfar, Monther A.
Warad, Ismail
AlDamen, Murad A.
author_sort Khanfar, Monther A.
collection PubMed
description In the title compound, [RuCl(2)(C(5)H(14)N(2))(C(18)H(15)P)(2)], the Ru(II) atom is six-coordinated, forming a slightly distorted octa­hedral geometry, with two chloride ions in an axial arrangement, and two P atoms of two triphenyl­phosphane and two chelating N atoms of the bidentate 2,2-dimethyl­propane-1,3-diamine ligand located in the equatorial plane. The average Ru—P, Ru—N and Ru—Cl bond lengths are 2.325 (18), 2.1845 (7) and 2.4123 (12) Å, respectively.
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spelling pubmed-30069092010-12-30 trans-Dichlorido(2,2-dimethyl­propane-1,3-diamine)­bis­(triphenyl­phosphane)ruthenium(II) Khanfar, Monther A. Warad, Ismail AlDamen, Murad A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(2)(C(5)H(14)N(2))(C(18)H(15)P)(2)], the Ru(II) atom is six-coordinated, forming a slightly distorted octa­hedral geometry, with two chloride ions in an axial arrangement, and two P atoms of two triphenyl­phosphane and two chelating N atoms of the bidentate 2,2-dimethyl­propane-1,3-diamine ligand located in the equatorial plane. The average Ru—P, Ru—N and Ru—Cl bond lengths are 2.325 (18), 2.1845 (7) and 2.4123 (12) Å, respectively. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006909/ /pubmed/21587674 http://dx.doi.org/10.1107/S1600536810019276 Text en © Khanfar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khanfar, Monther A.
Warad, Ismail
AlDamen, Murad A.
trans-Dichlorido(2,2-dimethyl­propane-1,3-diamine)­bis­(triphenyl­phosphane)ruthenium(II)
title trans-Dichlorido(2,2-dimethyl­propane-1,3-diamine)­bis­(triphenyl­phosphane)ruthenium(II)
title_full trans-Dichlorido(2,2-dimethyl­propane-1,3-diamine)­bis­(triphenyl­phosphane)ruthenium(II)
title_fullStr trans-Dichlorido(2,2-dimethyl­propane-1,3-diamine)­bis­(triphenyl­phosphane)ruthenium(II)
title_full_unstemmed trans-Dichlorido(2,2-dimethyl­propane-1,3-diamine)­bis­(triphenyl­phosphane)ruthenium(II)
title_short trans-Dichlorido(2,2-dimethyl­propane-1,3-diamine)­bis­(triphenyl­phosphane)ruthenium(II)
title_sort trans-dichlorido(2,2-dimethyl­propane-1,3-diamine)­bis­(triphenyl­phosphane)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006909/
https://www.ncbi.nlm.nih.gov/pubmed/21587674
http://dx.doi.org/10.1107/S1600536810019276
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