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(E)-3-(3-Chlorophenyl)-N-(4-hydroxy-3-methoxybenzyl)acrylamide
In the title compound, C(17)H(16)ClNO(3), the 4-hydroxy-3-methoxybenzyl group is planar [maximum atomic deviation = 0.0138 (16) Å] and is nearly perpendicular to the chlorobenzene ring, making a dihedral angle of 84.67 (4)°. The chlorobenzene and amide groups are located on the opposite sides o...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006917/ https://www.ncbi.nlm.nih.gov/pubmed/21587920 http://dx.doi.org/10.1107/S1600536810022713 |
Sumario: | In the title compound, C(17)H(16)ClNO(3), the 4-hydroxy-3-methoxybenzyl group is planar [maximum atomic deviation = 0.0138 (16) Å] and is nearly perpendicular to the chlorobenzene ring, making a dihedral angle of 84.67 (4)°. The chlorobenzene and amide groups are located on the opposite sides of the C=C bond, showing an E configuration. The relatively long C=O bond distance of 1.2364 (19) Å and the short C—N bond distance of 1.341 (2) Å suggest electron delocalization in the amide fragment. Intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonding is present in the crystal structure. |
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