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1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2,4,6-trinitro­phenolate)

In the title compound, C(6)H(14)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the cation possesses crystallographically imposed twofold rotation symmetry. In the crystal structure, the cation and anions are linked into a trimeric aggregate by inter­molecular N—H⋯O hydrogen bonds. The trimeric units are further c...

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Detalles Bibliográficos
Autor principal: SiMa, Weiwei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006919/
https://www.ncbi.nlm.nih.gov/pubmed/21587824
http://dx.doi.org/10.1107/S1600536810021021
Descripción
Sumario:In the title compound, C(6)H(14)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the cation possesses crystallographically imposed twofold rotation symmetry. In the crystal structure, the cation and anions are linked into a trimeric aggregate by inter­molecular N—H⋯O hydrogen bonds. The trimeric units are further connected by π–π inter­actions [centroid–centroid distances = 3.507 (2)–3.660 (3) Å], forming layers parallel to the bc plane.