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1,4-Diazoniabicyclo[2.2.2]octane bis(2,4,6-trinitrophenolate)
In the title compound, C(6)H(14)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the cation possesses crystallographically imposed twofold rotation symmetry. In the crystal structure, the cation and anions are linked into a trimeric aggregate by intermolecular N—H⋯O hydrogen bonds. The trimeric units are further c...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006919/ https://www.ncbi.nlm.nih.gov/pubmed/21587824 http://dx.doi.org/10.1107/S1600536810021021 |
Sumario: | In the title compound, C(6)H(14)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the cation possesses crystallographically imposed twofold rotation symmetry. In the crystal structure, the cation and anions are linked into a trimeric aggregate by intermolecular N—H⋯O hydrogen bonds. The trimeric units are further connected by π–π interactions [centroid–centroid distances = 3.507 (2)–3.660 (3) Å], forming layers parallel to the bc plane. |
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