1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2,4,6-trinitro­phenolate)

In the title compound, C(6)H(14)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the cation possesses crystallographically imposed twofold rotation symmetry. In the crystal structure, the cation and anions are linked into a trimeric aggregate by inter­molecular N—H⋯O hydrogen bonds. The trimeric units are further c...

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Detalles Bibliográficos
Autor principal: SiMa, Weiwei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006919/
https://www.ncbi.nlm.nih.gov/pubmed/21587824
http://dx.doi.org/10.1107/S1600536810021021
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author SiMa, Weiwei
author_facet SiMa, Weiwei
author_sort SiMa, Weiwei
collection PubMed
description In the title compound, C(6)H(14)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the cation possesses crystallographically imposed twofold rotation symmetry. In the crystal structure, the cation and anions are linked into a trimeric aggregate by inter­molecular N—H⋯O hydrogen bonds. The trimeric units are further connected by π–π inter­actions [centroid–centroid distances = 3.507 (2)–3.660 (3) Å], forming layers parallel to the bc plane.
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spelling pubmed-30069192010-12-30 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2,4,6-trinitro­phenolate) SiMa, Weiwei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(14)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the cation possesses crystallographically imposed twofold rotation symmetry. In the crystal structure, the cation and anions are linked into a trimeric aggregate by inter­molecular N—H⋯O hydrogen bonds. The trimeric units are further connected by π–π inter­actions [centroid–centroid distances = 3.507 (2)–3.660 (3) Å], forming layers parallel to the bc plane. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006919/ /pubmed/21587824 http://dx.doi.org/10.1107/S1600536810021021 Text en © Weiwei SiMa 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
SiMa, Weiwei
1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2,4,6-trinitro­phenolate)
title 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2,4,6-trinitro­phenolate)
title_full 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2,4,6-trinitro­phenolate)
title_fullStr 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2,4,6-trinitro­phenolate)
title_full_unstemmed 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2,4,6-trinitro­phenolate)
title_short 1,4-Diazo­niabicyclo­[2.2.2]octane bis­(2,4,6-trinitro­phenolate)
title_sort 1,4-diazo­niabicyclo­[2.2.2]octane bis­(2,4,6-trinitro­phenolate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006919/
https://www.ncbi.nlm.nih.gov/pubmed/21587824
http://dx.doi.org/10.1107/S1600536810021021
work_keys_str_mv AT simaweiwei 14diazoniabicyclo222octanebis246trinitrophenolate

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