9-Benzyl-10-methyl­acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(21)H(18)N(+)·CF(3)OS(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems. These dimers are further linked by C—H⋯π inter­actions. The cations and anions are connected by C—H⋯O, C—F⋯π and S—O⋯π inter­a...

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Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Zadykowicz, Beata, Krzymiński, Karol, Sikorski, Artur, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006932/
https://www.ncbi.nlm.nih.gov/pubmed/21587794
http://dx.doi.org/10.1107/S160053681001963X
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author Trzybiński, Damian
Zadykowicz, Beata
Krzymiński, Karol
Sikorski, Artur
Błażejowski, Jerzy
author_facet Trzybiński, Damian
Zadykowicz, Beata
Krzymiński, Karol
Sikorski, Artur
Błażejowski, Jerzy
author_sort Trzybiński, Damian
collection PubMed
description In the crystal structure of the title compound, C(21)H(18)N(+)·CF(3)OS(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems. These dimers are further linked by C—H⋯π inter­actions. The cations and anions are connected by C—H⋯O, C—F⋯π and S—O⋯π inter­actions. The acridine and benzene ring systems are oriented at a dihedral angle of 76.8 (1)°with respect to each other. The acridine moieties are either parallel or inclined at an angle of 62.4 (1)° in the crystal structure.
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spelling pubmed-30069322010-12-30 9-Benzyl-10-methyl­acridinium trifluoro­methane­sulfonate Trzybiński, Damian Zadykowicz, Beata Krzymiński, Karol Sikorski, Artur Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(21)H(18)N(+)·CF(3)OS(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems. These dimers are further linked by C—H⋯π inter­actions. The cations and anions are connected by C—H⋯O, C—F⋯π and S—O⋯π inter­actions. The acridine and benzene ring systems are oriented at a dihedral angle of 76.8 (1)°with respect to each other. The acridine moieties are either parallel or inclined at an angle of 62.4 (1)° in the crystal structure. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006932/ /pubmed/21587794 http://dx.doi.org/10.1107/S160053681001963X Text en © Trzybiński et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trzybiński, Damian
Zadykowicz, Beata
Krzymiński, Karol
Sikorski, Artur
Błażejowski, Jerzy
9-Benzyl-10-methyl­acridinium trifluoro­methane­sulfonate
title 9-Benzyl-10-methyl­acridinium trifluoro­methane­sulfonate
title_full 9-Benzyl-10-methyl­acridinium trifluoro­methane­sulfonate
title_fullStr 9-Benzyl-10-methyl­acridinium trifluoro­methane­sulfonate
title_full_unstemmed 9-Benzyl-10-methyl­acridinium trifluoro­methane­sulfonate
title_short 9-Benzyl-10-methyl­acridinium trifluoro­methane­sulfonate
title_sort 9-benzyl-10-methyl­acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006932/
https://www.ncbi.nlm.nih.gov/pubmed/21587794
http://dx.doi.org/10.1107/S160053681001963X
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AT zadykowiczbeata 9benzyl10methylacridiniumtrifluoromethanesulfonate
AT krzyminskikarol 9benzyl10methylacridiniumtrifluoromethanesulfonate
AT sikorskiartur 9benzyl10methylacridiniumtrifluoromethanesulfonate
AT błazejowskijerzy 9benzyl10methylacridiniumtrifluoromethanesulfonate

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